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2016 Vol. 35, No. 4

Display Method:
Perspectives on karst biogeochemistry
LI Qiang, JIN Zhen-jiang
2016, 35(4): 349-356. doi: 10.11932/karst20160401
Abstract:
In the karst process, the dissolution of the carbonate minerals, such as CaCO3 and CaMg(CO3)2, is essential in the presence of water and under a normal atmospheric temperature/pressure environment, involving the consumption of atmospheric CO2 into Ca2+/Mg2+ and the anion bicarbonate. Usually, the hydration of CO2 to HCO3- is relatively slow, especially in the forward direction, of which the CO2 are originated from different sources resulting from a complex interaction between geology, climate and hydrology, and also biological components. In this paper, previous researches in the fields of karst, geochemistry and biology were overviewed. The main points of this paper are to address the issues on karst biogeochemistry process, the biological action involving chemical weathering of carbonate rocks and element cycle, the gas circulation in the interface between soil and atmosphere, organic pollutants in the karst environment, as well as the function of microorganism relating to karst carbon cycle, with a major focus on water-soil erosion and rocky desertification. To understand the above problems, the function of earth creatures in the karst environment must be valued.
Stable carbon isotope fractionation (δ13C) of microalgae on CO2 assimilation
ZHAO Li-hua, WU Yan-you, XIE Teng-xiang, LI Hai-tao, ZHANG Kai-yan, HANG Hong-tao
2016, 35(4): 357-362. doi: 10.11932/karst20160402
Abstract:
A study on the stable carbon isotopic fractionation (δ13C) in the process of CO2 assimilation of microalgae is very significant to investigate the role of microalgae in estimate of potential carbon dioxide (CO2) sink. However, till now it is yet unknown how to measure the fractionation on CO2 assimilation of microalgae in vivo. Bidirectional tracers, which two types of sodium bicarbonate have different δ13C-PDB values, are used as the carbon isotope labeling to establish the method of calculation of the fractionation value in this study. Furthermore, the different proportions of metabolic pathways of inorganic carbon utilization are quantified by the fractionation value in microalgae. The carbon isotope fractionation (δ13C) value of three types of algae, Chlamydomonas reinhardtii (CR), Chlorella pyrenoidosa(CP), and compound algae collected from surface water of Hongfeng Lake, are 15.3‰, 14.8‰, and 21.7‰, respectively in this paper. The difference of the fractionation values are closely related to cell size of these microalgaes. That means, the bigger cell size of microalgae, the greater the resistance produces and the longer the reaction time of process in the CO2 assimilation. This leads to greater fractional values. The percent share of bicarbonate ions calculated by the fractionation values are 100%, 81.1% and 97.8% respectively in Chlamydomonas reinhardtii, Chlorella pyrenoidosa and compound algae. The results demonstrate that the main pathway of inorganic carbon utilization of microalgae is the bicarbonate ions in karst lakes.
Computation of fracture water flow based on discrete fracture network model
WANG Jin-li, CHEN Xi, ZHANG Zhi-cai, KANG Jian-rong, GAO Man
2016, 35(4): 363-371. doi: 10.11932/karst20160403
Abstract:
Discrete fracture network (DFN) model is one of the most effective means to study the flow path and groundwater flow in a fractured rock aquifer. Based on statistical distributions of geometrical and hydraulic parameters of fractures, two-dimensional discrete fracture network is realized through using Monte Carlo stochastic simulation technology. Fracture network connectivity is determined based on adjacency matrix of undirected graph and backbone or distinct preferential flow path is preserved using recursive algorithm. Flow model of DFN is built using numerical-analytical method on the basis of cubic law and seepage continuity equation; and this model is used to solve fluid flow under different boundary conditions. The results show that this method can simulate the total flux into the regional domain in the direction of hydraulic gradient, head at internal nodes and flow in channels as well as variation of flow direction at internal nodes. It provides a practical and feasible method for flow estimation of regional karst fissure water.
Exploration of risk assessment method towards groundwater contamination in karst region: A case study in Disu underground river system basin
CUI Ya-feng, HE Jiang-tao, WANG Man-li, ZHAO Yue-kun, WANG Fei
2016, 35(4): 372-383. doi: 10.11932/karst20160404
Abstract:
Groundwater contamination risk assessment is of great significance in protecting, managing and reasonably utilizing karst groundwater. In this paper, various methods in regards with groundwater contamination risk assessment were comparatively reviewed. As a result, a new groundwater contamination risk assessment method which is suitable for small karst area was proposed, in view of the disadvantage of the current methods and based on European model which has often been used to assess the groundwater vulnerability in a research area. By considering the contaminant attenuation effect, this research focused on the quantification of the reduction coefficient of contaminant load. Moreover, based on GIS spatial analysis, the assessment of the environmental risk of groundwater contamination in a research area was performed. To verify the suitability of the method developed, a case study was conducted in Disu karst underground river system. The results show that risk of groundwater contamination in the research area is relatively low. The areal size with moderate and high groundwater contamination risk is 424.41 km2, accounting for 39.03% of the total research area. The high-risk areas include Disu town, Dongmiao town, Liuye town, with frequent human activities, and the middle and lower reaches of Disu underground main river stream. Furthermore, for this research it is suggested that the spatial characteristics of the groundwater contamination risk in the areas is affected not only by the natural factors such as lithology, gradient, development degree of karst and etc.,but also by human activities.High groundwater contamination risk of the region is mainly attributed to the gentle terrain slope, dense karst network and strong human activities.
Time lags variance of groundwater level response to precipitation of Jinan karst spring watershed in recent 50 years
QI Xiao-fan, WANG Yu-shan, YANG Li-zhi, LIU Zhong-ye, WANG Wei, LI Wen-peng
2016, 35(4): 384-393. doi: 10.11932/karst20160405
Abstract:
Recent 50 years, both groundwater level data and precipitation data were devided into several time periods in this paper. The time lags of groundwater levels to precipitation were quantitatively analyzed by using the method of cross wavelet analysis; and the relationships between the time lags and groundwater abstraction etc. were also studied by correlation analysis. The results show that, (1)The main periodicities of both groundwater level and precipitation are 1 a. (2)The time lags of groundwater levels of discharge area are 83.44-161.24 d and 88.62-150.56 d by the two divisions, while the time lags of runoff area are 67.87-81.66 d and 76.58-82.21 d, respectively, which is significantly less than the time lags of discharge area. (3) According to precipitation, a trend that the less the precipitation and the larger the time lag can be concluded in both runoff and discharge areas. (4)Taking into account the groundwater levels, the time lag becomes larger while the groundwater level is lower in discharge area. This case does not occur in runoff area. (5)Correlation relationship is obvious between the time lag and groundwater exploitation and spring discharge. The larger the exploitation and the less the spring discharge, the larger the time lags. Analyzing time lag variances of groundwater levels to precipitation can provide knowledge on their nonlinear coupling processes, which will be benefit to the forecast of groundwater levels.
The characteristics of karst cave ancient floodplain sediment and environment evolution: A case study in Shanwang cave
YANG Zhen-hua, LI Po, WU Ke-hua
2016, 35(4): 394-401. doi: 10.11932/karst20160406
Abstract:
To reveal the influence of karst cave sediments on the sedimentary environment and the sedimentary process, this study was conducted in the middle range of Shanwang cave, Guizhou, in conjuction with previous studies of the cave development and associated geological information of the area. The sediment grain size analysis was done and on this basis Sahu's formula was employed to analyze the correlation of sedimentary environment and the sediment particle gradation, from which the evolution of sedimentary environment in different cave sedimentary cycles was assessed. The results show that, (1) in the surface of ancient floodplain, the sediments comprise very fine sand, silt and clay, with an average content of 94.42%, where there is an intercalated coarse gravel layer; (2) the sedimentary pattern was represented by the uniform deposition process which was dominated by steady flow over the cave floodplain; as a result the average sediment particle size was 637 μm, with a maximum size of 864.2 μm; (3) According to the characteristics of granularity, the ancient floodplain deposition can be divided into three layers deposited in different sedimentary environments; the first layer is 404-275 cm in thickness, the second one is 285-165 cm thick and the third 165-0 cm in thickness. The results provide important information for the determination of regional erosion datum and the study of crustal movement of the area. In the meantime, it provides an strong evidence for the research of paleoclimate of the Shanwang cave area.
Discoveries of Ailuropoda-Stegodon Fauna from Shuanghe Cave
GAO Zhan-dong, Jean Bottazzi, ZHAO Xin-nan, HE Wei, Eric Sanson, LI Po, CHENG Hai
2016, 35(4): 402-406. doi: 10.11932/karst20160407
Abstract:
In this paper, the status quo of Quaternary fauna fossils in Shuanghe Cave in the course of the previous expeditions and in Guizhou province was overviewed. Research on Quaternary fauna in the Shuanghe Cave in Suiyang County is still in its infancy, and reasons were discussed. In order to accelerate the research process, the discovery of Ailuropoda-Stegodon fauna fossils in the cave with a Sino-French joint expedition this year was reported. The result from uranium series dating (ICP-MS) shows that the carbonate inclusion of the panda fossils can be dated back to 6.75 million years ago. It was suggested that this fauna might survive in the Middle Pleistocene-early Late Pleistocene. The Pleistocene mammalian fossils and associated stratigraphic data will provide important information to the Quaternary study in Guizhou,especially in northern Guizhou.
Characteristicts of geological heritages, adventure tourism and speleotherapy tourism of Hongguoshu area in Suiyang, Guizhou
LI You-wei, SHI Xiao-zhi, HE Wei, LI Po
2016, 35(4): 407-413. doi: 10.11932/karst20160408
Abstract:
For increasing the knowledge of Hongguoshu scenic area, as well as offering popular science for the adventure and speleotherapy in the other karst tourist areas, this paper studies the characteristics of geological heritages of Hongguoshu scenic area, with data derived from field survey and previous studies. On this basis, this study further overviews the tourism products such as via ferratas hiking SRT, speleotherapy and etc.in the Hongguoshu Area. The result shows that, (1) There are abundant geological heritages in the Hongguoshu area which is idea holiday resort with highly aesthetic, distinctive and science popularization values; (2) Adventure tourism and speleotherapy tourism products have good feasibility in the karst area, they are entertaining and functional with a great potential of further tourism development; they can be the model of other scenic spots in karst area of multiplex development.
Analysis on the relationship between climatic and environmental factors in karst caves: An example from Zhijin Cave of Guizhou Province
YIN Chao, ZHOU Zhong-fa, CAO Ming-da, ZHANG Jie, ZHANG Qiang, ZHANG Shao-yun, PAN Yan-xi
2016, 35(4): 414-424. doi: 10.11932/karst20160409
Abstract:
Zhijin Cave as a tourist cave with a poorly closed environment connects with the outside via cave tunnel and many shafts and fractures. Due to the change of atmospheric environment and tourist volume fluctuation in summer and autumn, the CO2 concentration and humidity in the cave are usually higher than that of spring and winter. The correlation statistical analysis of the cave CO2 concentration, air pressure, air temperature and humidity with data obtained in January 2015 to January 2016 was performed. Temperature and CO2 concentration showed a negative correlation, and the correlation coefficients in summer and autumn were -0.72876 and -0.65616, respectively. However, in spring and winter the temperature and CO2 concentration was positively correlated, and the correlation coefficients of the two quarter were 0.85452 and 0.93846, respectively. Except for the relationship between humidity and temperature, the fitting degrees between the other environmental factors on the basis of SINE function fitting are comparatively high, which fall in the range of 0.6-0.8. According to the analytical results, the relationship between climatic and environmental factors is believed to be heavily impacted by the seasonal tunnel air exchange, atmospheric precipitation, cave water, overlying soil CO2, tourists who visit the cave, cave lightening facilities and etc.
Characteristics of spatial temporal variation of air environment in tourism cave and its cause analysis: A case study of the Dafeng cave in Suiyang county, Guizhou Province
PAN Yan-xi, ZHOU Zhong-fa, LI Po, CAO Ming-da, ZHANG Shao-yun, YIN Chao, ZHANG Jie
2016, 35(4): 425-431. doi: 10.11932/karst20160410
Abstract:
This study is to explore the fact and causes of the spatial and temporal variation of air environment in the Dafeng cave. 10 monitoring points were set up along the horizontal tunnel of Dafeng cave; and CO2 concentration,temperature and relative humidity of each monitoring point had been continuously monitored for a period of 11 months (from October 2015 to August 2016). Through the analysis of these data gained from the cave, its air environment variation can be summarized as follows,(1)The air environment elements (i.e. CO2, temperature, relative humidity) of the tunnel show an obvious seasonal variation. In general, their values are low in winter and high in summer; (2)Due to weak air exchange with the external in the seasons of spring, summer and autumn, the CO2 concentration and humidity gradually increase to the deep in the cave, while the temperature gradually decreases, and all of which stabilize at a certain depth of the cave tunnel owing to very limited cave air exchange with the outside. In winter time, the temperature curve does not indicate the abrupt change, but the CO2 content and humidity fluctuate much in vertical direction from the roof to the bottom; (3)Vertically (from the bottom to the cave roof), the values of CO2 concentration and humidity are different and they are higher at the bottom than those of the cave roof. To the further deep cave these three environmental elements get stabilized.
Morphological comparison and analysis of the causes of pothole formation in karst cave: An example from Shuanghe Cave of Guizhou Province
ZHANG Jie, ZHOU Zhong-fa, LI Po, CAO Ming-da, YIN Chao, ZHANG Shao-yun, ZHANG Qiang
2016, 35(4): 432-438. doi: 10.11932/karst20160411
Abstract:
Shuanghe Cave is located in Wenquan town, 12 km west of Suiyang county, Guizhou Province. It is a multi-layer cave system, developed in the dolomite strata in the upper Cambrian Loushanguan group. The landscape of the area comprises peak-cluster depression, peak-cluster valley and peak-cluster canyon. Faults and joints of cave area are well developed, of which joints trend in the direction of NS and NW. Controlled by the lithologies and geological structures, the underground river has been developed, where the potholes occur along the underground river of Yinhe and Xiangshui caves in Shuanghe Cave system. The annual mean temperature of the area is 15.5 ℃ and annual precipitation is about 1,210 mm. In order to compare the difference in pothole morphology and formation cause in the two caves, the pothole geometric features including the length of hole axes, hole depth and trend direction of the potholes long axis were measured in the field, by using measuring tape and laser range device. Statistical results show that distribution area of the potholes in Yinhe cave is small, with a considerable number of the pothole. However, potholes in Xiangshui cave are widely distributed, with thousands of the holes occur along both sides of the cave channel. Geometrically, the pothole oblateness of Yinhe cave is generally higher than that of Xiangshui cave, while the hole depth/width ratio of theYinhe cave is higher than that of Xiangshui cave. Morphologically, the potholes are dominated by both “V” and inverted “Ω” types in the Yinhe cave, while in the Xiangshui cave the potholes of inverted “Ω” type are predominant. This is closely related to the two cave water dynamic condition, geological structure, bed load, bedrock, weathering.
Effects of different land use and soil type on the migration of heavy metals in a pyrite smelting area
HONG Tao, XIE Yun-qiu, ZHAO Yi, Yang Li-chao
2016, 35(4): 439-445. doi: 10.11932/karst20160412
Abstract:
The objective of this work is to understand the impact of the Weihe pyrite smelting on the surrounding environment and migration of soil heavy metals due to different land uses and soil types. In total 12 surface soil samples and 28 deep soil samples on 4 profiles were collected from the cultivated land and woodland in or near the smelting area. The total and available contents of heavy metals and soil chemical and physical properties were analyzed. The results indicate that the concentrations of total lead (as Pb) and zinc (as Zn) in the soils are generally less than the threshold levels of China Environmental Quality Standard for Soils(GB 15618-1995 Class II), while the concentrations of total and available cadmium (as Cd) in soils exceed the soil background values of Guizhou Province. Cd has the highest value, while the difference between Pb and Zn is relatively small. The total contents of Zn and Cd in the farmland soils first increase and then decrease at depth, but Pb keeps a decreasing trend. The available contents of Pb and Zn decrease with the depths, while Cd shows a fluctuating trend. The total and available contents of the three heavy metals in woodland soils exhibit a decreasing trend at depth. There is a remarkable positive correlation between the total contents and available contents of Pb, Zn and Cd, and also a remarkable positive correlation among the total contents of the three heavy metals in woodland lime soils, but not in farmland soils. A soil environment with frequent disturbances and an acidic condition is favorable for the migration of heavy metals in a vertical direction.
Study on the dynamic change of soil moisture in karst area:A case of Huaxi district in Guiyang City
YAN Meng-meng, ZHOU Zhou, WANG Ji, GU Xiao-ping, XIAO Jian-yong
2016, 35(4): 446-452. doi: 10.11932/karst20160413
Abstract:
Huaxi district is located in the south of Guiyang City in Guizhou Province. It bestrides an area between E106°27′-106°52′and N26°11′-26°34′, with a land area of 958.56 km2 and a population size of 4.9×105. Soils are predominated by yellow and lime soils. The area is characterized by humid subtropical monsoonal plateau climate, with the average annual temperature of 14.9 ℃, the average annual rainfall of 1,178.3  mm, annual sunshine time of about 1,278 h, the average annual relative humidity of 78% and frost-free period of about 270 d. 94% of the landmass is karst landform, represented by low hills and lowlands. In order to explore the dynamic change of soil moisture with rainfall, we used Excel 2003, SPSS software and the cluster analysis method to analyze the relationship between the soil moisture and precipitation in the study area. Results show that, (1) The vertical change in soil moisture content is significant at depth in 2013 and 2015, which can be divided into active layer (0-10 cm), sub-active layer (10-30 cm) and relatively stable layer (30-100 cm); (2) The dynamic change of soil moisture is mainly affected by rainfall and evaportranspiration, which can be accurately reflected by the above relationship at the 10-30 cm deep soil layer; (3) The dynamic change of soil moisture has an obvious character of seasonal fluctuation, of which the spring and winter can be identified as the soil water recharge period, while the soil moisture consumption takes place in summer and autumn. The main reasons for the change of soil moisture in karst area are the result of the interaction of rainfall and soil evaporation, plant transpiration and vegetation consumption.
The coupling relationship between sustainable use of land and harmonious development of ecological environment of Chongqing from 1999 to 2013
LUN Dan, ZHOU Wen-zuo, SU Wei-ci
2016, 35(4): 453-459. doi: 10.11932/karst20160414
Abstract:
A rational assessment of the coupling relationship between land use and ecological environment is the premise to ensure that the land resources can be sustainably utilized for the economic development in a region. Chongqing is partially situated in karst area with a vulnerable eco-environment where in the past the environmental impact due to unchanging land use pattern has been severe. Therefore, a well coupled relationship between land use and eco-environment is very important for the sustainable development in the area. In this paper, this relationship and associated reasons for various coupling are fully analyzed, by using principal component analysis through the application of statistical software SPSS. The results show that, land use index increased year by year from 1999 to 2013, which was attribute to the large-scale construction of urbanization. In the same period, the ecological environment index show that the overall eco-environmental quality in the area had a steady increase, except for a declined state from 2000 to 2004. The results also show that, coupling development degree has risen from 0.3874 which implies a mild recession and loss of the land use type, to 0.7540 which suggests an intermediate coordinated development and economic domination type from 1999 to 2013. However, the situation was changed in 2011 when the land use index was for the first time less than the ecological environment index. As a result, basic types of the coupling development was shifted from an ecology-oriented development to an economy-dominated one; the mode of regional economic development changed from a land use controlled type to an eco-environment constrained one; and the ecological environment benefit lagged behind the economic benefits from the use of land resources. Due to the improvement of overall land resource utilization level and ecological environment, the coupling relationship has been transformed from the imbalance development into coordinated one. At present stage, we should stick to such an idea that both intensive utilization of land resources and immediate measures for the resource protection should be implemented simultaneously. Meanwhile, it is encouraged to optimize the economic structure and innovative technology, to develop cycling economy and clean energy, and to maintain a relatively stable eco-environment dynamics to ensure that the utilization of land resources in Chongqing can be sustainably implemented.