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2012 Vol. 31, No. 3

Display Method:
Simulation experiment for weathering of culture relic on carbonate rock palisades in Longmen grottoes
GU Ning, WU Jiang-ying, DUAN Feng-jun, HU Chao-yong, RUAN Jiao-yang
2012, 31(3): 227-233. doi: 10.3969/j.issn.1001-4810.2012.03.001
Abstract:
In order to research the weathering mechanism on the surface of carbonate rock by condensation water in Longmen grottoes, in light of monitoring for condensation water and CO2 concentration on the spot, the weathering process is stimulated with a self-made indoor experimental tester that enabling stimulating temperature and humidity conditions, providing external source of CO2, and monitoring the reaction process. It shows that condensation water can dissolve the surface of carbonate rock, and that the mass loss and porosity of the rocks will increase when CO2 is added. Based on 78 tests, it proves that the mass loss of limestone sample is 0.077%~0.088% and the porosity increased from 0.39%~0.40% to 0.71%~0.74%; mass loss of dolomite sample is 0.032%~0.038% and the porosity increased from 0.61%~0.68% to 0.77%~0.85%; the average corrosion depth and velocity of limestone is 89.475 μm and 0.0956 μm/h, those of dolomiteis 36.865 μm and 0.0575 μm/h. It is concluded that the corrosive weathering is of great damage to the culture relic in Longmen grottoes. Key words: grotto; carbonate rock; condensation water; culture relic on palisades; weathering; simulation experiment
Simulation experiment for the dissolution of carbonate rocks of the Yingshan formation on the northern slope of Tazhong uplift
SHE Min, ZHU Yin, SHEN An-jiang, ZHENG Xing-ping, HE Xun-yun
2012, 31(3): 234-239. doi: 10.3969/j.issn.1001-4810.2012.03.002
Abstract:
Dissolution experiment and microscopic observation are carried out to research micro-corrosion mechanism of carbonate rocks. The corrosion process and micro features of three types of carbonate rocks in the Yingshan formation on the northern slope of Tazhong uplift are studied in this paper. The results show that the dissolution quantities of three kinds of carbonate rocks, parry bioclastic limestone, dolomitic limestone and mud-crystal grain limestone, are almost the same. Because of the selective dissolution for composition and microstructure of rocks, micro-corrosion characteristics of these three kinds of carbonate rocks are significantly different. The surface of sparry bioclastic limestone and mud-crystal grain limestone are overall reduced by corrosion. The calcites of dolomitic limestone are eroded and lowered to formmould pores. The dolomites of dolomitic limestone are eroded into honeycomb-like pores that protruding on the rock surface. The inter-crystal fractures of dolomite are enlarged by dissolution and become interconnected. That is of important significance for reservoir and permeability of oil, gas and groundwater.
Analysis on impact factors of karst development in Dao County iron and manganese mining area of Hunan
CHEN Liang-jing, YAO Teng-fei, ZHOU Xin
2012, 31(3): 240-247. doi: 10.3969/j.issn.1001-4810.2012.03.003
Abstract:
The karst development at iron-manganese mining area in Dao County, Hunan Province is mainly controlled by lithology, landform and fracture. There are many forms of karst landforms, including cave, Underground River, karren, groove, funnel, ponor and uvala, with obviously heterogeneity features. Karst is most developed, one in the 2nd-4th layer dolomitic limestone and dolomite of the Shetianqiao Group and the Xikuangshan Group of the upper Devonian system that having the highest CaO content; and another in the aquiclude junction of between marl and argillaceous limestone of the Xikuangshan Group lower members. There are 260 caves in the Shetianqiao Group, that accounting for 96.7%of the total. In plane view, the karst is the most developed in the covered karst flat area at the central and the northern parts with 54.8% of cave ratio; the next developed of karst is in the karst-hills at the eastern and southern parts with 40.4% of cave ratio. Vertically, the karst growth gets weaker with depth, 237 caves, accounting for 86.5% of the total, are uncovered by drill at 0~220 m in elevation; and 28 caves, accounting for 10.2% of the total, are uncovered by drill at -150~0 m; but no caves or corrosion below-400 m. Tectonically, fracture zone affects karst development. There are 209 caves with relatively high cave filling ratio, accounting for 76.3% of the total, along the fracture zone.
Grayscale and climatic instructions of modern stalagmite from artificial tunnel inside the Fairy Hillin Hubei
YANG Xun-lin, YUAN Dao-xian, ZHANG Yue-ming, HUANG Fan, SUN Yu-chuan, YANG Yan
2012, 31(3): 248-252. doi: 10.3969/j.issn.1001-4810.2012.03.004
Abstract:
A 9-year contemporary stalagmite got from an artificial tunnel inside the Fairy Hill in the Three Gorges area is used as the research object, and high-resolution stalagmite gray level series on interannual-seasonal time scale are obtained by means of digital image analysis in the study. In comparison with the local monitoring meteorological data, it is found that the grayscale of the contemporary stalagmite is of similar variation tendency with the monitoring precipitation and temperature data. That is to say, the greater the precipitation and the higher the temperature are, the bigger the grayscale of the contemporary stalagmite and vice versa. It is still need further study whether the leading factor affecting the gray scale is precipitation or the temperature.
Indications of the hydrogen and oxygen isotopes in precipitation for climate change in Huanglong, Sichuan
WANG Hai-jing, ZHANG Jin-liu, LIU Zai-hua
2012, 31(3): 253-258. doi: 10.3969/j.issn.1001-4810.2012.03.005
Abstract:
The slope and constant of the meteoric water line in Huanglong are both smaller than the global meteoric waterline, which is related to the evaporation enrichment of heavy isotopes as raindrops fall in unsaturated atmosphere, and the climate in Huanglong has been getting warmer and drier in the recent decades. The notable amount effect of the isotopes in precipitation illustrates the vapor in Huanglong precipitation is mainly from low latitude ocean. The seasonal variation in the excess deuterium and the amount effect of the hydrogen and oxygen isotopes in precipitation reflect slight precipitation and strong evaporation and thus strong enrichment of heavy isotopes in dry season of Huanglong with the dry air for being influenced by continental air mass. It is influenced by low latitude marine vapor with moist air, heavy precipitation and slight evaporation in rainy season, so the enrichment of heavy isotopes is slight and the rainfall is characterized with low stable isotopic ratio. Therefore, it can be deduced that the amount effect of the isotopes in precipitation is resulted by the difference in vapor origin; the temperature effect is not notable in Huanglong where the monsoon climate effect restrained and covered up the temperature effect.
Cyclic utilization of sludge and flyash to improve the soil quality in karst rocky desert
CHEN Jin-wu, SUN Yi-ming, ZHANG Xian-qiang, WANG Feng-ying, SUN Ji-wei, ZHANG Hong, SUN Min
2012, 31(3): 259-264. doi: 10.3969/j.issn.1001-4810.2012.03.006
Abstract:
Soil in karst rocky desert is applied with sludge-flyash composites of different sludge to flyash proportion in this experiment, and the effects of sludge-flyash composites on soil physicochemical properties, water-holding capacity and heavy metal accumulation in Festuca arundinacea are studied accordingly. The results show that the heavy metal contents like Cu, Mn, Zn and Cd in the sludge are remarkably decreased, the soil pH enhanced to about 7 and the soil physicochemical properties improved obviously after applying flyash; and that the soil water-saturation coefficients is enhanced by 1.95 times, the time of water retention elongated about 7d, the soil N, P increased and the biomass of Festuca arundinacea is also enhanced remarkably. So, it can yet be regarded as an effective method to ecologic rehabilitation for karst rocky desert. But it is not suitable to apply sludge repeatedly for the half-life period of the heavy metals in the sludge is long and the heavy metals are difficult to be thoroughly eliminated, and the heavy metals themselves are of serious eco-toxicity.
Effects of different land-uses on the features of water-stable aggregates in karst and clasolite areas in Maocun, Guilin
YANG Hui, ZHANG Lian-kai, YU Shi, CAO Jiao-hua
2012, 31(3): 265-271. doi: 10.3969/j.issn.1001-4810.2012.03.007
Abstract:
In order to make a systematic study on the effects of different types of land-use on the distribution characteristics of soil water-stable aggregates(WSA),soil samples are collected from dry land, paddy field, forestland and shrub land in karst and clasolite areas in Maocun, Guilin, a typical karst area in Southwest China. The results show that land-use has a significant impact on the distribution and the composition of WSA (p<0.05) in soils in both karst area and clasolite area. Comparing to traditional farmland, the proportions of WSA (that>5mm and 0.25mm) in natural forest and shrub soils are significantly increased. Moreover, the stability of the WSA is also increased. This shows that aggregate stability in less disturbed land-use is higher than that in more disturbed land-use by human. Mean weight diameter (MWD) and Geometric mean diameter(GMD)in shrub land in karst area are increased by 185% and 179% respectively comparing with that in dry land, while 361% and 481% respectively comparing with that in paddy field. The MWD and GMD in forestland are increased by 65% and 43% comparing with that in dry land, while 167% and 198% comparing with the paddy field. The increasing range of MWD and GMD in shrub land in clasolite area, comparing with that in dry land and paddy field, are 103% and 134%, 15% and 32% respectively. The MWD and GMD in forestland, comparing with that in dry land and paddy field, are increased by 117% and 152%, 23% and 43%. The results also show that after having been greatly affected by human activities, the quality of rendzina soil in karst area degrades faster than that of red soil in clasolite area and the WSA stability decreases steeply, all of which indicate that the soil environment in karst area is vulnerable.
Laboratory experiment on water-rock interaction of the karst fracture water after recharged with roof rainwater
ZHU Zhong-zhu, WANG Wei-ping, JIANG Ying-kui, ZHOU Ya-qun
2012, 31(3): 272-278. doi: 10.3969/j.issn.1001-4810.2012.03.008
Abstract:
Simulation experiment is carried out to test the corrosive interaction between the Ordovician system limestone samples taken from the west campus of the Jinan University with the mixed water of different groundwater to rainwater ratio. The water-rock interaction among the original groundwater, aquifer media and rainwater being recharged is analyzed by means of determination of pH and electrical conductivity as well as several convention ions and using hydro-geochemical modeling software PHREEQC. The results show that,(1)after the groundwater and rainwater being mixed with each other, the CO2 pressure in the mixed water gradually decreases under the influence of temperature increase and decarbonation along with the oscillation; (2) Ca2+ concentration slightly decreases when mixing ratios of groundwater and rainwater are 9∶1, 7∶3 and 5∶5 respectively, while other ions concentration does not change obviously; (3)saturation indexes of calcite, dolomite and gypsum decrease along with reaction time, and saturation indexes of calcite and dolomite decrease obviously along with the increases of recharging rainwater amount, from 0.23~-0.39 and 0.05~-0.97 when the ratio of groundwater to rainwater being 9∶1 and from -0.34~-0.62 and -1.59~-2.57 when the ratio of groundwater to rainwater being 1∶9 respectively, which indicating that the rainwater is able to increase the corrosion to calcite and dolomite or even the whole aquifer and that the more the rainwater amount, the more obvious and stronger the corrosive effect; (4) rainwater recharge can only lead limited corrosion amount, so it won’t cause obvious impact on the stability of the aquifers around the well.
Hydrochemistry and variation of δ13C DIC of the Qingmuguan underground river in Chongqing
QIU Shu-lan, JIANG Yong-jun, ZHANG Xing-bo, CAO Min, HU Yi-jun, LIAO Wen-e
2012, 31(3): 279-288. doi: 10.3969/j.issn.1001-4810.2012.03.009
Abstract:
In order to determine the source of dissolved inorganic carbon and the matter in the Qingmuguan underground river system, the underground river system is monitored from April, 2010 to January, 2011, and the chemical components, the dissolved inorganic carbon content and δ13C DIC as well as their influencing factors are analyzed. Furthermore, detailed analysis is made to some monitor points in the ploughing season in 2010. The results show that(1)the type of the Qingmuguan underground river water is Ca-HCO3 that is affected mainly by water-rock action and rainfall; (2) the molar ratio of (Ca2++Mg2+)/HCO3- in the groundwater varies from 0.6 to 0.72 and is averaged 0.67,whichindicating the carbonate dissolution is controlled by CO2, HNO3 and H2SO4 in the soil under the C3 vegetation cover; (3)the HCO3- from carbonate dissolution by carbonic acid account for 56.16% to 81.25% of the total HCO3- concentration in groundwater with a mean percentage of 66.96%,whilethe HCO3- from carbonate dissolution by sulphuric and nitric acids make up 18.75% to 43.84%of the total HCO3- concentration in groundwater with a mean percentage of 33.04%; (4)the δ13C DIC in groundwater varies from -8.17‰ to -13.68‰ with an average value of -10.53‰,the average value of δ13C DIC in ploughing and dry season is -9.25‰ and -12.29‰ respectively, which indicates there is a significant perturbation to the cycling and export of inorganic carbon by agricultural activities in karst underground river system.
Analysis on the chemical characteristics of the atmospheric precipitation in Guilin
ZHANG Hong-bo, YU Shi, HE Shi-yi, LIU Qi, LI You-ling
2012, 31(3): 289-295. doi: 10.3969/j.issn.1001-4810.2012.03.010
Abstract:
Precipitation samples are collected and analyzed from January 2009 to December 2010 in the Guilin, Guangxi. The results show that (1)the pH value and the conductivity are 4.83 and 65 μS/cm respectively, the major anions are SO42- and NO3-,the major cations Ca2+ and NH4+ in the rainwater samples of Guilin; (2) major ion content, rainfall and conductivity assumes obvious seasonal variations, and among them the Ca2+ concentration is higher in summer and autumn, lower in spring and winter; (3)rainfall and TDS show good negative correlation,SO42-and NO3-,and Ca2+ and Mg2+ have good positive correlation; (4)in comparing the situations in the year of 2009-2010 to 1994-1995, the ion in the precipitation has increased by 1.16 times and pH increased to some extent, the rain still belongs to acid rain, and the contributing rate of the NO3-in the precipitation forth formation of acid rain in Guilin has obviously enhanced; (5)through continuous monitoring on rainfall of Guilin during 1 to 6, Mar. 2012, it is found that pH, conductivity and precipitation appear good correlation.
Study on the risk assessment on karst collapse in linear engineering
DAI Jian-ling, LEI Ming-tang, JIANG Xiao-zhen
2012, 31(3): 296-302. doi: 10.3969/j.issn.1001-4810.2012.03.011
Abstract:
In recent years, more and more high-level linear engineering such as high-level road and railway as well as oil pipeline passes through karst area. Karst collapse has become one of the major hidden dangers having to be faced in the linear engineering in karst area. At present, linear engineering project will conduct geological hazard zoning in the early phase. However, most of the works are qualitative and no special evaluation on karst collapse. Therefore, considering the influencing factors of karst collapse and different stage of linear engineering, different assessment methods and indicators are proposed from three levels, i.e. point, line and plane, and three examples are given at the same time, which will provide references for future linear projects that crossing the karst area. Plane and line assessment both use the Geographical Information System (GIS) and Analytic Hierarchy Process (A H P). Plane assessment suits for the feasibility stage that geological data are not clear. Assessment areais1 kilometer on both sides of the line and assessment factors are karst developed level, geological structure, landform type, sinkhole, subterranean river, vertical feature, karst spring and pumping wells distribution. Line assessment suits for preliminary design stage that geological data are clearer. Assessment areais15 meters on both sides of the line and assessment factors are bedrock lithology, line karst rate, soil thickness, soil properties, water level and relation between the water level and bedrock surface. And point assessment is suitable for the key sections, using the method of comprehensive analysis on the dynamic conditions of the karst collapse and the collapse resistance property of the earth. Three indexes, critical gradient, critical velocity and critical water level, which reflect the dynamic conditions of the groundwater, are used as the assessment factors.
Analysis on features and values of karst landscape in Leye-Fengshan Global Geopark
DENG Ya-dong, CHEN Wei-hai, ZHANG Yuan-hai, HUANG Bao-jian, LUO Shu-wen
2012, 31(3): 303-309. doi: 10.3969/j.issn.1001-4810.2012.03.012
Abstract:
Developed in the typical isolated island-liked karst region, the karst landscape in the Leye-Fengshan Global Geopark is featured by high fengcong, large caves, large karst gorges, large tanking group, karst windows group, large natural bridges and subterranean rivers. It is not only abundant in landscape types, but also complete in system and rare in landforms, which are valuable for sciences and sightseeing. According to genesis analysis and qualitative and quantitative evaluation on karst landscape in the geopark, five levels of landscape are classified: the top is the tiankeng group and karst windows group; the fourth is the natural bridges and karst gorges; the third is the high fengcong (doline and valley), poljes and large caves, the second is the through caves, karst springs and subterranean rivers, the bottom is shafts and sinkholes, which are the interspersed landscapes in the geopark.
The landscape characteristics and development idea of Fuxi Cave in Youyang, Chongqing
SUN Cheng-guo, DENG Ya-dong, YANG Hong-yong, CHU Bing, XIONG Wei, LI Jun-feng, LI Jiang-bo
2012, 31(3): 310-315. doi: 10.3969/j.issn.1001-4810.2012.03.013
Abstract:
Fuxi Cave is featured not only by unusual landscapes such as terraced field-like and human foot mark-like rimstones as well as stalagmites resembling to the general cap of the Qing Dynasty, but also b spectacular passages and chambers. The passages are 10 to 20 m in width, 20 to 35 m in height, and the chamberis 130 m in diameter at the bottom and 85 m high, where there is a huge stone waterfall of 43 high and 93 m wide, and a big column of 26 m high and 3.5 m in diameter with underground river flow in through and water streaming down the pool. In order to take advantage of landscape in Fuxi Cave and to pro mote tourism development in Youyang, the author proposed the development idea in the paper on the basis of analysis on the landscape characteristics and resources values that the" mysterious" should be highlighted people-oriented and outreach education strengthened, paying equal attention to exploitation and protection Furthermore, the author indicated that light design plays vital roles in displaying the" mysterious" feature in Fuxi Cave. And the white, blue, light green and green lights should be used on the canyon wall to form hierarchical display, the light green light be used in underground river performance, the cold and warm light combination be used on the flowstone and stalactites, and that the rock texture in the wall be lighted b white lamp.
Research progress of monitoring for dripping water environment in karst caves
PENG Ling-li, LI Ting-yong
2012, 31(3): 316-326. doi: 10.3969/j.issn.1001-4810.2012.03.014
Abstract:
Based on the study of the former achievement, it is concluded that the research process of monitoring for dripping water environment in karst caves mainly includes the following5 items.(1) Although the oxyhydrogen isotope component in dripping water basically represents the isotope components in the atmospheric precipitation, variation of the oxyhydrogen isotope in dipping water is diversity, due to the differences in the thickness and fissures of the overlying rocks above the cave, that leading to the differences in time response between the dripping water and the rainfall.(2) The chemical component of the dripping water mainly affected by the interaction among water, soil, bedrock and gas, and the dissolved inorganic carbon and organic acid is also affected by the vegetation form and density.(3) The physical condition of caves is an important factor that deciding whether the oxygen and carbon stable isotopes in the speleothem by dripping water can reach the state of equilibrium fractionation or not.(4)Because there are multiple solution and uncertainty in the indicating climatic change by components of the dripping water, the cave monitor should be extended to the overlying soil and vegetation outside of the cave to form a three-dimensional monitor system.(5) Mmonitoring for karst cave environments still needs synthetic comparison study under different natural conditions.
Preliminary study on technical specification system of karst cave survey
SHI Wen-qiang, LUO Shu-wen, DENG Ya-dong
2012, 31(3): 327-332. doi: 10.3969/j.issn.1001-4810.2012.03.015
Abstract:
There is no technical specification for karst cave survey in China at present. Based on the current situation of karst cave survey development, this paper studies the necessity and significance to construct a technical specification system for karst cave survey, and emphasizes its principles and thoughts. In light of system construction experience in other geological fields, the paper attempts to put forward the basic frame structure of the technical specification system for karst cave survey by means of hierarchical division, analyzes the key nodes of the system construction, and emphasizes that the specifications of cave measuring and database construction being the most important works in recent years. The specification system is the foundation of building the concrete specifications for various work contents in karst cave survey and has a great significance in developing the level of scientific research on karst cave and realizing higher social and economic value.
Uncertainty evaluations on the measurement of “carbon” in the research on karst carbon sink effect: A case for dissolved inorganic carbon
YU Jian-guo, DU Wen-yue, WANG Hua, ZHOU Xiao-hong
2012, 31(3): 333-338. doi: 10.3969/j.issn.1001-4810.2012.03.016
Abstract:
In order to set up an evaluation method for the uncertainty in determining dissolved inorganic carbon(DIC)in karst river basin by Non-dispersive Infrared(N DIR)absorption detection technique, the continuous propagation model of uncertainty is used to evaluate the uncertainties in determining DIC content of two typical karst groundwater samples. The main steps as follows: to fit the calibration curve by means of double-error regression firstly; and then to quantify each uncertainty component in the evaluation process lastly to obtain the synthetic uncertainty model for DIC determination results. Calculations through experimental results show that: (1) the main sources of the measurement uncertainty derive from sub-uncertainties of calibration solutions and calibration curve fitting as well as measurements process; (2) the lower the DIC content in groundwater samples, the greater the relative uncertainty of measurement results, and the sub uncertainty from the fitting of calibration curve makes the major contribution to the total uncertainty.
Discussion on article “Calculation of atmospheric CO2 sink formed in karst processes of karst-divided regions in China”
ZHANG Zhi-gan
2012, 31(3): 339-344. doi: 10.3969/j.issn.1001-4810.2012.03.017
Abstract:
A few calculated results and two important karst carbon sink data quoted in the article are being questioned. It is argued for: (1) A few basic parameters being used in the article are inaccurate. The calculated results are perhaps over-estimated in 3~4 times, and possibly 200 times larger for north China karst region and the buried karst region, respectively. (2)Because of intrinsic shortage of standard tablet method as a karst carbon sink determining tool, the “global karst carbon sink”(6.08×108 tC/a)obtained earlier is possibly overestimated by a factor of4 or so.(3)Estimated values for newly proposed items of the global water circulation model for carbon sink are thought to be significantly overestimated. The net global water circulation carbon sink is probably only a little larger than that owing to carbonate weathering of rocks. (4)Simplified formula for carbon sink calculation used in the article has accounted for only the DIC originated from atmosphere/soil CO2 corrosion but not for all of their origins. Therefore it should be corrected for non-atmosphere/soil CO2 corrosion further. At a global scale the correction factor is believed to be about 0.65. Consequently all results at this scale obtained earlier should be reduced by about 35%. (5) Actual global karst carbon sink flux eventually is probably of the order of 0.1±0.02 GtC/a, which is about6 times smaller than what is believed by authors of this article. Taking long term carbon cycle into account, given atmospheric carbon cycle nowadays is even in a strongly disturbed state, the net global karst carbon sink is probably much less than the order of0.01 GtC/a. It should not be considered as an important atmospheric carbon sink, especially comparing to the figure of photosynthesis (60 GtC/a).