| Citation: | PENG Ling-li, LI Ting-yong. Research progress of monitoring for dripping water environment in karst caves[J]. CARSOLOGICA SINICA, 2012, 31(3): 316-326. doi: 10.3969/j.issn.1001-4810.2012.03.014 | 
 
	                | [1] | Broecker W S. Massive iceberg discharges as triggers for global climate change[J]. Nature, 1994, 372:421—424. | 
| [2] | Yuan D X, Cheng H, Edwards R L, et al. Timing, duration, and transitions of the last interglacial Asian monsoon[J]. Science,2004,304(23):575—578. | 
| [3] | Fairchild I J, Smith C L, Baker A, et al. Modification and preservation of environmental signals in speleothems[J]. Earth-Science Reviews,2006,75:105—153. | 
| [4] | 程海,艾思本,王先锋,等.中国南方石笋氧同位素记录的重要意义[J].第四纪研究,2005,25(2):157—158. | 
| [5] | 郑立娜,周厚云,朱照宇.洞穴次生碳酸盐沉积的Mg/Ca与Sr/Ca比值研究进展——兼论洞穴次生沉积物Mg/Ca与Sr/Ca的影响机制[J].中国岩溶,2010,29(2):212—218. | 
| [6] | 周运超,王世杰.贵州凉风洞洞穴滴水水文水化学过程分析[J].第四纪研究,2005,25(2):208—215. | 
| [7] | 罗维均,王世杰.贵州凉风洞大气降水—土壤水—滴水的δ18O信号传递及其意义[J].科学通报,2008,53(17):2071—2076. | 
| [8] | Baker A, Genty D, Fairchild I J. Hydrological characterization of stalagmite drip waters at Grottede Villars, Dordogne, by the analysis of inorganic species and luminescent organic matter[J]. Hydrology and Earth System Sciences,2000,4:439—449. | 
| [9] | Cobb K M, Adkins J F, Partin J W, et al. Regional-scale climate influences on temporal variations of rainwater and cave drip water oxygen isotopes in northern Borneo[J]. Earth and Planetary Science Letters,2007,263:207—220. | 
| [10] | Hendy C H. The isotopic geochemistry of speleothems-Ⅰ: The calculation of the effects of different modes of formation on the isotopic composition of speleothems and their applicability as paleoe limatic indicators[J]. Geochimica et Cosmochimica Acta,1971,35:801—824. | 
| [11] | Harmon R S, Thompson P, Schwarez H P, et al. Late Pleistocene paleo climates of North America as inferred from stable isotope studies of speleothems[J]. Quaternary Research, 1978,9:54—70. | 
| [12] | Henning G J, Grun R. Brunnacker K. Speleothems, travertines, and paleo climates[J]. Quaternary Research,1983,20:1—29. | 
| [13] | Gascoyne M. Paleo climate determination from cave calcite deposits[J]. Quaternary Science Reviews, 1992,11:609—632. | 
| [14] | 李红春,顾德隆,赵树森,等.北京石花洞地区水系氢氧同位素及氚含量研究——石花洞研究系列之一[J].地震研究,1996,18(4):325—328. | 
| [15] | 谭明,南素兰.中国季风区降水氧同位素年际变化的“环流效应”初探[J].第四纪研究,2010,30(3):620—622. | 
| [16] | 罗维均,王世杰,刘秀明.中国大气降水δ18O区域特征及其对古气候研究的意义[J].地球与环境,2008,36(1):47—55. | 
| [17] | 李晖,蒋忠诚,王月,等.新疆地区大气降水中稳定同位素的变化特征[J].水土保持研究,2009,16(5):157—161. | 
| [18] | 张平中,陈一萌,Jhonsno K R,等.甘肃武都万象洞滴水与现代石笋同位素的环境意义[J].科学通报,2004,49(15):1529—1531. | 
| [19] | Wackerbarth A, Scholz D, Fohlmeister J, et al. Modelling theδ18O value of cave drip water and speleothem calcite[J]. Earth and Planetary Science Letters, 2010,299:387—397. | 
| [20] | 田立德,马凌龙,余武生,等.青藏高原东部玉树降水中稳定同位素季节变化与水汽输送[J].中国科学D辑,2008,38(8):986—992. | 
| [21] | 李彬,袁道先,林玉石,等.桂林地区降水、洞穴滴水及现代洞穴碳酸盐氧碳同位素研究及其环境意义[J].中国科学(D辑),2000,30(1):81—87. | 
| [22] | Vaks A, Bar-Matthews M, Ayalon A, et al. Paleo climate reconstruction based on the timing of speleothem growth and oxygen and carbon isotope composition in a cave located in the rain shadow in Israel[J]. Quaternary Research,2003,59:182—193. | 
| [23] | 刘鑫,宋献方,夏军,等.黄土高原岔巴沟流域降水氢氧同位素特征及水汽来源初探[J].资源科学,2007,129(3):59—66. | 
| [24] | Pape J R, Banner J L, Mack L E, et al. Controls on oxygen isotope variability in precipitation and cave drip waters, central Texas,USA[J]. Journal of Hydrology, 2010,85:203—215. | 
| [25] | 章新平,姚檀栋,刘晶淼,等.不同时间尺度下的稳定同位素变化[J].冰川冻土,2005,25(4):428—432. | 
| [26] | Bar-Matthews M, Ayalon A, Gilmour M, et al. Sea-land oxygen isotopic relationships from planktonic foraminifera and speleothems in the Eastern Mediterranean region and their implication paleo rainfall during interglacial intervals[J]. Geochimica et Cosmochimica Acta, 2003,67:3181—3199. | 
| [27] | Bar-Matthews M, Ayalon A, Matthews A, et al. Carbon and oxygen isotope study of the active water-carbonate system in the karstic Mediterranean cave: implications for paleo climate research in semiarid regions[J]. Geochimica et Cosmochimica Acta,1996,60:337—347. | 
| [28] | Li T Y, Shen C C, Li H C, et al. Oxygen and carbon isotopic systematics of aragonite speleothems and water in Furong Cave, Chong Qing, China[J]. Geochimica et Cosmochimica Acta,2011,75:4140—4156. | 
| [29] | Wang Y J, Cheng H, Edwards R L, et al. A high-resolution absolute-dated late Pleistocene monsoon record from Hulu Cave, China[J]. Science,2001,294:2345—2348. | 
| [30] | Wang Y J, Cheng H, Edwards R L, et al. The Holocene Asian Monsoon: Links to Solar Changes and North Atlantic Climate[J]. Science,2005,308:854—857. | 
| [31] | Wang Y J, Cheng H, Edwards R L, et al. Millennial-and orbital-scale changes in the East Asian monsoon over the past 224,000 years[J].Nature,2008,451:1090—1093. | 
| [32] | Cheng H, Edwards R L, Broecker W S, et al. Ice Age Terminations[J]. Science, 2009, 326: 248—252. | 
| [33] | Clemens S C, Prell W L, Sun Y B, et al. Orbital-scale timing and mechanisms driving Late Pleistocene Indo-Asian summer monsoon: Reinterpreting cave speleothem δ18O[J]. Paleoceanography, 2010, 25,PA4207,doi: 10.1029/2010PA001926. | 
| [34] | Francesco S R P, David S B, Kerim H N, et al. Chinese stalagmite δ18O controlled by changes in the Indian monsoon during a simulated Heinrich event[J]. Nature Geoscience, 2011, doi: 10.1038/NGEO1169. | 
| [35] | 庞洪喜,何元庆,张忠林.重要海—气—天文事件与新德里季风季水中δ18O的关系[J].冰川冻土,2004,26(1):42—47. | 
| [36] | 柳鉴容,宋献方,袁国富,等.中国东部季风区大气降水δ18O的特征及水汽来源[J].科学通报,2009,54(22):3521—3531. | 
| [37] | Cerling T E. The stable isotopic composition of soil carbonate and its relationship to climate[J]. Earth and Planetary Science Letters,1984,71:229—240. | 
| [38] | 李红春,顾德隆,StottL,等.北京石花洞石笋500年来的δ13C记录与古气候变化及大气CO2浓度变化的关系[J].中国岩溶,1997,16(4):285—296. | 
| [39] | Andy B, Emi I, Peter L, et al. Elevated and variable values of 13C in speleothems in a British cave system[J]. Chemical Geology,1997,136:263—270. | 
| [40] | Mc DermottF. Palaeo-climate reconstruction from stable isotope variations in speleothems: a review[J]. Quaternary Science Reviews,2004,23:901—918. | 
| [41] | 姜修洋,李志忠.洞穴次生碳酸盐稳定同位素古气候重建研究进展[J].亚热带资源与环境学报,2010,5(3):64—72. | 
| [42] | 李廷勇,李红春,向晓晶,等.碳同位素(δ13C)在重庆岩溶地区植被—土壤—基岩—洞穴系统运移特征研究[J].中国科学,2012,42(4):526—535. | 
| [43] | Tremaine D M, Froelich P N, Yang Wang. Speleothem calcite farmed in situ: Modern calibration of δ18O and δ13C paleo climate proxies in a continuously-monitored natural cave system[J]. Geochimica et Cosmochimica Acta,2011,75,4929—4950. | 
| [44] | Mattey D, Lowry D, Duffet J, et al. A 53 year seasonally resolved oxygen and carbon isotope record from a modern Gibraltar speleothem: Reconstructed drip water and relationship to local precipitation[J]. Earth and Planetary Science Letters,2008,269:80—95. | 
| [45] | Katz A. The interaction of magnesium with calcite during crystal grow that 25–90℃ and one atmosphere[J]. Geochim Cosmochim Acta,1973,37:1563—1586. | 
| [46] | Mucci A. Influence of temperature on the composition of magnesium calcite over grpwths preci-pitated from sea water[J]. Geochim Cosmochim Acta,1987,51:1977—1984. | 
| [47] | Dever L, Duran R, Fontes J C, et al. Etude pedogenetique et isotopique des neoformations de calcite dans un sol sur craie; caracteristiques et origines[J]. Geochimica et Cosmochimica Acta, 1983,47:2079—2090. | 
| [48] | 杨琰.洞穴石笋高精度ICP—MS铀系年代学与西南岩溶地区古气候变化研究[D].武汉:中国地质大学,2006. | 
| [49] | Epstein S, Buchsbaum R, Lowenstam H A, et al. Revised carbonate-water isotopic temperature scale[J]. Geological Society of America,1953,64:1315—1325. | 
| [50] | O’Neil J R, Clayton R N, Mayeda T. Oxygen isotope fraction ation in divalentmetal carbonates[J]. Journal of Chemical Physics,1969,30:5547—5558. | 
| [51] | 李红春,顾德隆,陈文寄,等.利用洞穴石笋的δ18O和δ13C重建3000a以来北京地区古气候和古环境——石花洞研究系列之三[J].地震地质,1997,19(1):77—85. | 
| [52] | Fohlmeister J, Scholz D, Kromer B, et al. Modelling carbon isotopes of carbonates in cave drip water[J]. Geochimica et Cosmochimica Acta,2011,75:5219—5228. | 
| [53] | Polag D, Scholz D, Mühlinghaus C, et al. Stable isotope fractionation in speleothems: Laboratory experiments[J]. Chemical Geology,2010,279:31—39. | 
| [54] | Michler P, Banner L, Stern A, et al. Stable isotope variations in modern tropical speleothems: Evaluating equilibrium vs. kinetic isotope effects[J]. Geochimica et Cosmochimica Acta, 2004, 68:4381—4393. | 
| [55] | Mickler J, Stern A, Banner L. Large kinetic isotope effects in modern speleothems[J]. Geological Society of America Bulletin,2006,118:65—81. | 
| [56] | Dreybrodt W, Scholz D. Climatic dependence of stable carbon and oxygen isotope signals recorded in speleothems: From soil water to speleothem calcite[J]. Geochimica et Cosmochimica Acta,2011,75:734—752. | 
| [57] | Dorale J A, Liu Z H. Limitations of hendytest criteriain judging hepaleo climatics uitability of speleothems and the need for replication[J]. Journal of Caveand Karst Studies,2009,71:73—80. | 
| [58] | Baldini J U L, McDermott F, Fairchild I J. Structure of the 8200 year cold event revealed by a speleothem trace element record[J]. Science,2002,296:2203—2206. | 
| [59] | Cruz F R, Burns S J, Jercinovic M, et al. Evidence of rainfal l variations in Southern Brazil from trace element ratios (Mg/Ca and Sr/Ca) in a Late Pleistocene stalagmite[J]. Geochimica et Cosmochimica Acta, 2007,71:2250—2263. | 
| [60] | Zhou H Y, Feng Y X, Zhao J X, et al. Deglacial variations of Sr and 87Sr/86Sr ratio recorded by a stalagmite from Central China and their association with past climate and environment[J]. Chemical Geology, 2009,268:233—247. | 
| [61] | 胡进武,王增银,周炼,等.岩溶水锶元素水文地球化学特征[J].中国岩溶,2004,23(1):37—42. | 
| [62] | Musgrove M, Banner J L. Controls on the spatial and temporal variability of vadose drip water geochemistry: Edwards Aquifer, central Texas[J]. Geochimica et Cosmochimica Acta, 2004, 68:1007—1020. | 
| [63] | 王明达,胡超涌,周炼,等.围岩地球化学组成及气候对洞穴滴水水化学的影响——以湖北清江和尚洞为例[J].地质科技情报,2010,29(3):97—103. | 
| [64] | Frumkin A, Stein M. The Sahara-East Mediterranean dust and climate connection revealed by strontium and uranium isotopes in a Jerusalem speleothem[J]. Earth and Planetary Science Letters, 2004,217:451—464. | 
| [65] | Fairchild I J, Baker A, Borsato A S, et al. Annual to sub-annual resolution of multiple trace element trends in speleothems[J]. Journal of the Geological Society,2001,158:831—841. | 
| [66] | VanBeynen P E, Soto L, Pace-Graczy k K. Paleo climate reconstruction derived from speleothem strontium and δ13C in Central Florida[J]. Quaternary International,2008,187:76—83. | 
| [67] | Johnson K R, Hu C, Belshaw N S, et al. Seasonal trace-element and stable isotope variations in a Chinese speleothem: the potential for high resolution paleomonsoon reconstruction[J]. Earth and Planetary Science Letters,2006,244:394—407. | 
| [68] | Gascoyne M. Trace-element partition coefficients in the calcite water system and their paleo climatic significance in cave studies[J]. Journal of Hydrology,1983,61:213—222. | 
| [69] | 马志邦,李红春,夏明,等.距今3ka来京东地区的古温度变化:石笋Mg/Sr记录[J].科学通报,2002,47(23):1829—1834. | 
| [70] | Fairchild I J, Pauline C, Treble. Trace elements in speleothems as recorders of environmental change[J]. Quaternary Science Reviews,2009,28:449—468. | 
| [71] | Fairchild I J, Borsato A, Tooth A F, et al. Controls on trace element (Sr-Mg) compositions of carbonate cave waters: implications for speleothem climatic records[J]. Chemical Geology, 2000, 166:255—269. | 
| [72] | Tooth A F, Fairchild I J. Soil and karst aquifer hydrological controls on the geochemical evolution of speleothem - forming drip waters, Crag Cave, southwes t Ireland[J]. Journal of Hydrology, 2003,273:51—68. | 
| [73] | McDonald J, Drysdale R, Hill D, et al. The hydrochemical response of cave drip waters to sub-annual and inter-annual climate variability, Wombeyan Caves, SE Australia[J]. Chemical Geology, 2007,244:605—623. | 
| [74] | 王新中,班凤梅,潘根兴.洞穴滴水地球化学的空间和时间变化及其控制因素——以北京石花洞为例[J].第四纪研究,2005,25(2):255—264. | 
| [75] | 李清.重庆地区末次冰期以来石笋的微量元素及古气候记录研究[D].重庆:西南大学,2009. | 
| [76] | 李珊英.洞穴石笋ICP-MS微量元素分析技术与豫西MIS8/9时段古气候变化研究[D].重庆:西南大学,2012. | 
| [77] | 周运超,王世杰.贵州七星洞滴水的水文水化学特征及其意义[J].水文地质工程地质,2006,1:52—57. | 
| [78] | 傅平青,刘丛强,尹祚莹,等.腐殖酸三维荧光光谱特性研究[J].地球化学,2004,33(3):301—308. | 
| [79] | Baker A, Genty D, Smart P L. High-resolution records of soil humification and palaeoclimate from variations in speleothem luminescence excitation and emission wavelengths[J]. Geology, 1998, 26(10):903—906. | 
| [80] | Baker A, Genty D. Fluoresce ncewavelength and intensity variations of cave waters[J]. Journal of Hydrology,1999,217:19—34. | 
| [81] | 谢兴能,王世杰,周运超,等.洞穴滴水溶解有机碳三维荧光光谱特征及其对环境的响应:以贵州4个洞穴系统为例[J].科学通报,2007,52(23):2781—2784. | 
| [82] | 黄咸雨,蒲阳,崔景伟,等.湖北清江和尚洞洞穴滴水脂肪酸分布特征及其古生态意义[J].第四纪研究,2007,27(3):401—407. | 
| [83] | Li X L, Wang C F, Huang J H, et al. Seasonal variation of fatty acids from drip water in Heshang Cave, central China[J]. Applied Geochemistry,2011,26:341—347. | 
| [84] | 张美良,朱晓燕,林玉石,等.桂林盘龙洞滴水的物理化学指标变化研究及其意义[J].地球与环境,2009,37(1):1—9. | 
| [85] | Sp?tl C, Fairchild I J, Tooth A F. Cave air control on drip water geochemistry, Obir Caves (Austria): Implications for speleothem deposition in dynamically ventilated caves[J]. Geochimica et Cosmochimica Acta,2005,69:2451—2468. | 
| [86] | Baldini J U L,McDermott F, Fairchild I J. Spatial variability in cave drip water hydro chemistry: Implications for stalagmite paleoclimate records[J]. Chemical Geology, 2006, 235:390—404. | 
| [87] | Baldini J U L, McDermott F, Hoffmann D L, et al. Very high-frequency and seasonal cave atmosphere PCO2 variability: implications for stalagmite growth and oxygen isotope-based paleo climate records[J]. Earth and Planetary Science Letters,2008,272:118—129. | 
| [88] | Kowalcz k A J, Froelich P N. Cave air ventilation and CO2 outgassing by radon-222 modeling: How fast do caves breathe?[J]. Earth and Planetary Science Letters,2010,289:209—219. | 
| [89] | Faimon J, ?telcl J, Sas D. Anthropogenic CO2-flux into cave atmosphere and its environmental impact: A case study in the Císaˇrsk Cave (Moravian Karst, Czech Republic) [J]. Science of the Total Environment,2006,369:231—245. | 
