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2017 Vol. 36, No. 3

Display Method:
Zoning of environmental geology and functions in karst fault-depression basins
WANG Yu, ZHANG Hua, ZHANG Gui, WANG Bo, PENG Shuhui, HE Raosheng, ZHOU Chuiqiong
2017, 36(3): 283-295. doi: 10.11932/karst20170316
Abstract:
Intermountain basins in karst plateaus, known as karst fault-depression basins, resulted from subsidence and dissolution of fault blocks induced by Cenozoic tectonic uplift. Determined by the mechanism dominated by these processes, these basins are characterized by distinct geomorphic zones, intense neotectonic movements, uneven distribution of water resources, prominent zoning of soil and vegetation, significant vertical variations of climate, and large regional differences of human activities. Among them, the types and causes of the geomorphic landscapes are not only the overall reflection of the environmental geology but also the influencing factors of the habitat. Moreover, the types and causes of the landscapes are outstanding features for environmental geological zoning, as they can be easily observed and distinguished. Accordingly, the karst fault-depression basins can be divided into four environmental geological zones, (1) Erosion and karst mountain zone, (2) karst peak cluster-hill-valley zone, (3) deposition plain region, and (4) erosion and karst canyon. Each of these zones has different functions, i.e. (1) highly significant in ecological functions, (2) equally important in ecological and economic functions, and (3) most remarkable in economic functions. The functions of zone depend on the location of its associated river systems and the macro influence of its regional ecology. In this article, we show the three-dimensional maps detailing the environmental geological zones of karst fault-depression basins. These maps directly display the details of each zone and their interrelationships, revealing the structure of their water cycling systems and mass transport processes.
Characteristics of sedimentary geology of parent rock at the Xueyudong Cave and its impact on secondary sediments 
LEI Jiaqi, WU Kunyu, YOU Chao, JIANG Xuemeng, WANG Peng, JIANG Yongjun
2017, 36(3): 296-305. doi: 10.11932/karst20170302
Abstract:
The purpose of this work is to explore the effect of parent rock at caves on the cave system and its secondary sediments. Taking the Xueyudong Cave in Fengdu, Chongqing City as an example, we have made a detailed investigation to characterize its sedimentary geology, and study the relationship between sedimentary characteristics of parent rock and development of the cave and its secondary deposits. The results indicate that the parent rock of Xueyudong Cave belongs to the second member of Triassic Feixianguan Formation with main sedimentary facies as grain shoal. The main types of the rock are calcarenite grainstone, oolitic grainstone, calcirudite grainstone with a little micrite sandwiched. The predominant mineral compositions of the parent rock and secondary sediments are low magnesium calcite (LMC). The low Mg/Ca ratio of the parent rock led to a low Mg/Ca ratio of drip water in the cave, resulting in fast sideward growth of calcite crystals in LMC which are pure, coarse and of highly idiomorphic, that constitute the secondary sediments. The interbank, a relatively quiet sedimentary environment when the roof strata of the Xueyudong Cave were deposited, provided a good condition for the formation of thick-bedded limestone with high strength, thus helpful for development of the cave system. It means that the features of sedimentary geology of the parent rock in the cave can produce obvious influence on the evolution of the cave system and its secondary sediments. 
Characteristics of sedimentary microfacies of the Weining formation and its evolution in the Well Ziye-1, located in southern Guizhou Province,China
CHEN Houguo, PAN Ming, WANG Min, LU Shufan, LUO Xiangjian, ZHU Xun
2017, 36(3): 306-312. doi: 10.11932/karst20170303
Abstract:
The sedimentary rock of the Weining formation in the Ziyun area is characterized by platform margin algal mound deposits. Intensive study of borehole core from the well Ziye-1 shows that the sedimentary facies of the Weining formation is in total an upward grading sequence due to sea regression taking place under platform marginal reef to open platform environment. Meantime, it includes three subfacies as platform margin algal mound, restricted platform and open platform subfacies which can be further divided into six microfacies, i.e. biological bounded stone (SMF7), bioclastic argillaceous limestone with skeletal fragment/grain lime-argillaceous limestone (SMF10), oncolite rudstone/grained limestone (SMF13), aggregate grained limestone (SMF17)、homogen abiological micrite (SMF23)and clastic floating rock/ rudstone/breccia(SMF24).Sedimentary filling sequence of the Weining formation also consists of six sedimentary cycles which is lithologically similar to the above sedimentary microfacies. Each sedimentary cycle mainly comprises limestone algae clot formed under a platform marginal reef environment. However, the lithology slowly changes to bioclastic limestone produced in upward open platform condition. The results indicated that the Weining formation had experienced at least six times of sea-level fluctuation; Furthermore, The emergence of the Weining formation marked the end of the organic-rich mud shale of Dawuba formation produced at a slope facies along the northwest trough-basin margin in Luodian-Shuicheng area.
Carbonate rocks micro-characteristics and paleoenvironment significance in Baomoshan formation of early Permian of Shuicheng area,Guizhou Province,China
LONG Jianxi, CHEN Jianshu, PENG Chenglong, PAN Ming, GONG Guiyuan
2017, 36(3): 313-318. doi: 10.11932/karst20170304
Abstract:
Baomoshan formation of the Early Permian widely distributes in Shuicheng area; its lithology is a layer of carbonate rock with an intercalated thin clastic rocks. The composition of the carbonate rocks greatly changes in horizontal direction. In this study, 9 strip plane sections and more than 300 pieces of rock thin sections were measured and analyzed, from which 6 microfacies were summarized. These microfacies include abundant foraminiferal grainstone/ bioclastic lime-argillaceous limestone (SMF18), bioclastic lime-argillaceous limestone with skeletal fragment/grain lime-argillaceous limestone (SMF10), oncolite rudstone/ grained limestone (SMF13), sea lily enriched limestone (SMF12-CRIN), the shells of skeletal fragment(SMF11) and biological boundstone (SMF7). Through the comparison of different sections of rock structure, biological assemblage and hydrodynamic energy feature, the results show that the sedimentary environment of the Baomoshan formation was betweenopen sea platform and sea platform margin, with at least three times of the sea regression events from the northwest to the southeast in Shuicheng area, which coincide with the trough basin shrinking period deposition effect of this area.
Prediction of water inflow in karst-fracture of Fushan copper mine,Shandong Province,China
LI Duo, WEI Aihua, JIA Lei, CHEN Kang
2017, 36(3): 319-326. doi: 10.11932/karst20170305
Abstract:
Fushan copper mine is located in Fushan district, a hilly area in Yantai City, Shandong Province. Geologically, the region is composed of the lower Proterozoic Fenzishan group and Quaternary deposits, with lithology of the former mainly characterized by metamorphic rocks as marble which forms the wall rock of the mine. Karst landscapes are not fairly developed in the study region where, the major karst morphologies are corrosion fractures and pores. There are two type of aquifers, of which the fractured rock aquifer comprises mica schist intercalated with tremolite marble of the lower of Gangyu Formation and karst-fractured one consists of silicate marble and graphite marble of the upper of Jutun Formation. The ore body is mainly located in the lower of Gangyu Formation and the upper of Jutun Formation at the elevations above -450 m. In case of the large differences in lithologies, fractures development, groundwater storage and the permeability of aquifer media, the aquifer was conceptualized as a double-layered structure model, in which the parameter zones were accordingly yielded. Taking the mine dewatering with large drawdown and large discharge into account, a three-dimensional conceptual and anisotropic groundwater flow model was thus established. In this model, boundary conditions of the study area are controlled by regional faults, which can be conceptualized as confining and weak permeable boundaries. And the general head boundary was also used, so that the calculation of lateral inflow came from the change of water level to the weak permeable boundary. Meanwhile, the dewatering tunnel was generalized as drainage ditch. As a result, the total model area is 9.87 km2; and the hydrogeological conceptual model of the study area is regarded as a homogeneously anisotropic, double-deckered and 3D confined unsteady flow unity. On this basis, the numerical modelling for the groundwater seepage could be performed, which was examined and validated by using the data derived from multiple hole pumping tests and the long-term borehole observation. The drainage water inflow of the mine and normal water inflow in different years were predicted. The results showed that the drainage water inflow were 10,200 m3/d, 17,400 m3/d, 26,450 m3/d, 47,300 m3/d and 46,400 m3/d, respectively, at the -80 m, -200 m, -300 m, -400 m and -450 m levels , while normal water inflow were 7,500 m3/d, 14,060 m3/d, 28,070 m3/d, 37,200 m3/d and 41,600 m3/d, respectively. In all, it was feasible to establish the three-dimensional model of groundwater seepage in the study area according to the characteristics of karst development and groundwater flow. Meanwhile, the dewatering tunnel was generalized as drainage ditch and the general head boundary was used in the model, which make the conceptual model more reasonable.
Numerical simulation and optimal exploitation scheme for the karst groundwater recourses system of Fengshui spring basin in Zibo region, Shandong Province,China 
GUO Dapeng, KANG Fengxin, CHEN Huanliang, CHENG Jianmei, LUO Wei
2017, 36(3): 327-338. doi: 10.11932/karst20170306
Abstract:
The Fengshui karst spring system is the most important groundwater resources for water supply in the area of Zibo, Shandong Province. Due to serious industrial pollution of the previous water source in Dawu area, a new water source located in Liuzheng area is identified and explored to carry out the re-assessment of the karst groundwater resources availability and then come up with an optimal exploitation scheme. Through understanding hydrogeological conditions and establishing conceptual model of the study area, a three-dimensional, heterogeneous and anisotropic karst water model has developed by using FeFlow software, based upon the equivalent continuum porous media theory and using the data derived from the 16 year borehole monitoring data. The results of water balance calculation from 2000 to 2015 shows that the average groundwater recharge of the study area is 1.0447×106 m3/d and the average discharge is 8.027×105 m3/d, with a net positive surplus of 2.420×105 m3/d. The model prediction results for the optimal pumping of the karst groundwater suggest that, (1) To maintain the current groundwater exploitation with 3.591×105 m3/d in the Dawu area, the maximum exploitation should be 5.5×104 m3/d in the Liuzheng area, and the total exploitation in the Liuzheng-Dawu area is up to 4.141×105 m3/d; (2) To meet the need of maximum permissive groundwater exploitation in the Liuzheng-Dawu area, the maximum exploitation quantity can be decreased to 3.341×105 m3/d for Dawu area and increased to 8×104 m3/d for Liuzheng area.
Groundwater chemical characteristics of the Qiaojia district in Jinshajiang river valley, Yunnan, China
ZHANG Gui, HU Wenjun, LI Qian, LIU Jingjing, WANG Feng, ZOU Lei
2017, 36(3): 339-345. doi: 10.11932/karst20170307
Abstract:
The Qiaojia district in Jinshajiang river is about 15 km long, of which the cross section is topographically a trapezoidal valley with a relieved bottom and a maximum corrading depth up to 2,719 m. Along the valley karst aquifers develop well and Quaternary porous aquifers distribute at bottom of the valley. There are a number of springs appearing along the valley, which are main drinking water sources for the local residents. In order to better protect the valuable resources, in this research 38 representative springs in the area were selected for the study of groundwater hydrochemical characteristics. Water samples were collected at the end of the rainy season in November 2015 and the dry season period in April 2016, respectively. The samples were analyzed in Lab of Kunming Mineral Resources Monitoring and Testing Center, Ministry of Land and Resources. Sampling and analyzing of the water samples were carried out in accordance with the groundwater environmental monitoring technical specifications (HJ/T164-2004). The result shows that the groundwater chemical type is relatively simple, dominated by water types of HCO3-Ca, HCO3-Ca?Mg, HCO3-Mg?Ca.Basically, TDS(Total Dissolved Solids)concentration of groundwater presents a gradual increasing trend from slope recharge area to runoff zone and to discharge zone in valley area. The TDS concentration of porous groundwater is significantly higher than that of karst water. TDS in porous groundwater generally is greater than 400 mg/L and the ratio of calcium and magnesium (as Ca/Mg) is smaller than 4. In contrast, TDS in karst water is less than 350 mg/L and Ca/Mg is greater than 4. The major components of groundwater, HCO3-, Ca2+, Mg2+ and SO42-, show a positive correlation with TDS. In addition, based on the dynamics of chemical compositions, the origin and forming conditions of large springs in the Quaternary strata are analyzed as well. It is believed that the big spring water is a mixture of porous water and karst water, which is mainly fed by karst water.
Discussion and application of simulation methods for karst conduit flow based on MODFLOW
ZHAO Liangjie, XIA Riyuan, YANG Yang, SHAO Jingli, YI Lianxing, WANG Zhe
2017, 36(3): 346-351. doi: 10.11932/karst20170308
Abstract:
The Zhaidi karst underground river system is located in Guangxi of southwest China and is a typical karst spring catchment with a mean annual discharge of around 1.62 m3/s. The catchment area is about 31.05 km2, with altitudes ranging from 190 m to 820 m a.s.l, and is developed mainly in the Devonian limestones with the landform type of karst peak-cluster depression. Precipitation mainly takes place in spring and summer and mean annual precipitation recorded from 1971 to 2000 is about 1,601.1 mm. The Zhaidi karst underground river system is characterized by extremely anisotropic fractured carbonate rocks and well interconnected karst conduits. There are eight karst underground river sub-systems and many sky-windows, pools and sinkholes. According to tracer tests, these eight subsystems are also well connected each other, where the groundwater runs from the sinkhole G37 through the karst conduits toward the outlet G47. Although numerical technique is a powerful tool for evaluating karst water resources, but it is difficult to accurately depict the pipe flow in the karst conduits in the model due to its anisotropic property. In this paper, the conduit flow of the Zhaidi karst basin was studied, by using Drain module and River module in MODFLOW to simulate the karst conduit, for which the applicability of the modules was examined by the data derived from three observation boreholes respectively situated in the upstream, midstream and downstream of the basin. To observe the groundwater level fluctuation and to obtain the time series data, two boreholes (ZK7 and ZK8) were drilled on the conduit with intention. From upstream to downstream, the distances between sinkhole G37 and borehole ZK7, borehole ZK7 and ZK8, borehole ZK8 to outlet G47 are 1,400 m, 900 m, 140 m, respectively. In addition, the outlet G47 was equipped with a rectangle sharp-crested weir with a level logger installed. The results showed that there was a sudden change of the water table contour near conduit and the water level variation trend was simulated, which meant both of method could conform to the actual conduit features. At last, the principle of two simulation methods were analyzed which showed karst conduit in Drain module only played a drainage role without exchanging water, while in River module it could exchange water with aquifer. It can be concluded that River module is better that Drain module to simulate karst conduit flow.
Research progress and prospects of karst ecosystem services
HAN Huiqing, SU Zhihua
2017, 36(3): 352-358. doi: 10.11932/karst20170309
Abstract:
Karst ecosystems are typical vulnerable ecosystems in the world. The variety of ecosystems provides multiple important services such as water conservation, soil retention, biodiversity, grain production, water supply and leisure entertainment for humankind. However, excessive and unreasonable human activities in recent years has seriously destroyed karst ecosystem structure and influenced the effectiveness of karst ecosystem services. In order to clarify current situation and existing problem of karst ecosystem service research, this paper provides an in-depth overview in the progress and prospect of karst ecosystem service research on the basis of throughout literature and reference material surveys. The results showed that current classification of karst ecosystem service research has mainly transplanted the results of other fields, which ignored the particularity of karst ecosystems. The objects of assessment are water and soil conservation carbon fixation and forest products, but rarely involve cultural services. Quantity of value and material methods were widely applied in assessment of karst ecosystem services, whereas there was a lack of ecosystem service assessment based on these ecosystem processes. Current researches have much paid attention to spatial heterogeneity of karst ecosystem service value on the meso-small scale, while ignored the large-scale research. Research paradigm of karst ecosystem services was that the effects of land use change in ecosystem services value, which underlined the effects of land use changes and ecological projects on karst ecosystem services value. Few scholars paid close attention to the effects of climate change as well as coupling effects of natural factors and human factors on karst ecosystem services. We should enhance the study of karst ecosystem services based on the framework of "ecosystem structure and process-ecosystem function-ecosystem service" and establish unique classification system of karst ecosystem services. The applicability of the evaluation method of ecosystem services and development and utilization of evaluation model in karst region should be emphasized. Ecosystem services assessment in karst region at a large scale and associated cultural services assessment should be strengthened. We should expand the study of balance and synergy among karst ecosystem services as well as the effects of karst ecosystem services on human welfare. Spatial and temporal heterogeneity of tradeoff and synergy as well as the application of new techniques in tradeoff and synergy research should be given with more attention. Future research should attach great importance to comprehensive index system of human welfare and relationship between karst ecosystem services and human welfare in karst region. Finally, quantitative analysis of the impacts of natural factors and human factors on karst ecosystem services should be enhanced. 
Evaluation of ecological sensitivity in the city-encircling forest belt of Guiyang based on GIS and AHP
YU Yi’na, WANG Zhongmei
2017, 36(3): 359-367. doi: 10.11932/karst20170310
Abstract:
The city-encircling forest belt in Guiyang controls and regulates the ecological environment of the urban area. With development of urbanization construction recent years, this forest belt is suffering from damage to varied degrees. To protect the existing resources of the urban forest, it is necessary to conduct evaluation of ecological sensitivity. Based on the investigations of the geological environment and experimental data of this forest belt, we choose seven kinds of ecological sensitivity factors, i.e. stratigraphic lithology, geological structure, elevation, gradient, slope direction, the surface water and human activities. We employ GIS technology to make area division of the forest belt for each single factor. Using analytic hierarchy process (AHP) and spatial weighting methods, then we conduct a comprehensive division of ecological sensitivity to the entire forest belt. The results show that insensitive area accounts for 4.82% of the whole forest area, distributed in the northern part of study area. The slightly sensitive area accounts for 18.01%, distributed in the south, northeast and southeast. Medium sensitivity areas (42.91%) are distributed in the east, west and northeast. Highly sensitive areas occupy 29.61%, distributed in the northern region. Extremely sensitive areas account for 4.65% scattered in the forest belt. Aiming at the main ecological environment problems in every sensitive area, we propose the management and protection countermeasures which can provide a scientific basis to prevent and govern the forest ecological environment problems. At the same time, this research is also a scientific guidance for the ecological planning and construction of Guiyang in the future.
Analysis on the absorbing, transfer, restoration and adaptation mechanism of calcium in different peak forest plants in northern Guangdong Province,China
WEI Xinghu, LEI Li, LIU Shujuan, GUAN Gongcou
2017, 36(3): 368-376. doi: 10.11932/karst20170311
Abstract:
Thirty kinds of karst peak forest plants in the Shijiao village,Jiulong town,Yingde City, Guangdong Province(N24°08.113′,E112°51.855′, altitude, 121 m,height of hill 80 m)were selected as the object of quantitative analysis to reveal their adaptation to the karst soil environment rich in calcium. The measured variable included the total calcium content of rhizosphere soil, and root, stem, leaf and litter in different plants. The characteristics of utilization, store, and returning soil of calcium in different plants were analyzed based on the absorption coefficient, transfer rate, and return rates. In addition, adaptation mechanism for karst soil in different plants was classified based on the result of cluster analysis. The results show that,(1)The significant positive correlation between the total calcium content in plants and in rhizosphere soil shows the plants in karst peak forest have a good adaptation to karst soil. But the absorption coefficients have large differences among the different plants. The total calcium absorption coefficient of climbing plants is 1.21 times,1.22 times, and 1.30 times of trees, small shrubs and herbs, respectively. It means the climbing plants have a better adaptability to the karst environment.(2)There are large differences of total calcium in different living types of plants in the leaf, stem, and root, of which the average total calcium content are 1.08 times,1.07 times 1.17 times of trees, respectively, and 1.39 times and 1.82 times of herbs in leaf and root, respectively. The total calcium content has a tendency of root>leaf>stem.(3)The litter is the main way through which calcium in plants returns to the soil. The rates of 30 kinds of karst peak forest plants are between 22.06%-103.84%, among which herbs has the biggest rate, and tree has the second, and shrubs has the smallest, which are 67.18%,58.72%, 55.90%, respectively. (4)The results of cluster analysis based on the total calcium content of rhizosphere soil, root, stem, leaf, and litter show different adaptation ways of plants to karst soil, which are classified into four categories, abundant calcium-high absorption-low restoration, few calcium-low absorption-high restoration, more calcium-high absorption-medium restoration, and more calcium-medium absorption-medium restoration. There are 26 kinds of plants belong to the last one, implying that the most of plants in karst peak forests have a good adaptation to the karst high-calcium environment through continual absorption, steady accumulation and high-rate restoration.
Impact of agricultural tourism activity on the soil environment in karst regions
WANG Shuai, DENG Jia, DENG Fuling, LUO Yunzhong, XIE Deti, MO Lian, YANG Sisi, YANG Juan
2017, 36(3): 377-386. doi: 10.11932/karst20170312
Abstract:
In order to clarify the influence of leisure agriculture tourism activity, which is booming in eastern Sichuan, on the soil ecological environment and provide a scientific basis for assessing the impact of agricultural tourism activity on the environment in the future. This paper takes the soil sample regions of tour trail on both sides of Chongqing Beibei Jinguoyuan(leisure sightseeing orchard) (hereinafter refers to as the "Jinguoyuan") and Huangjiaomen Tongliang area, Qicaimengyuan (yellow door modern agricultural park) (hereinafter refers to as "Qicaimenyuan") as the research objects. Using the quadrat method of two parks on either side of the main route, the soil samples are investigated. Through on-site survey and laboratory analysis on samples, this work systematically studied the soil environment affected by the distance, the ecological index hit rule and its potential risk. Results show that in both the areas affected by the agricultural recreation, the soil moisture content, soil organic matter, soil total nitrogen and alkaline hydrolysis nitrogen decrease with the decreasing distance from trails. The soil bulk density rises with the decrease of the distance from trails, while the soil pH value only in the Qicaimengyuan presents a rising trend with the decrease of the distance from trails. Each index of the affected range is mainly concentrated in the range of 4 m. The trampling index analysis shows that the two parks are in a state of mild trample. The soil humus layer and herb have not been completely destroyed and soil ecological environment under the natural state can be restored. Evaluation the soil heavy metal content of the two parks indicates that in general every area of soil is in a clean environment or still clean state. The Cd and Pb content in the part of the sample zone reaches the security alert (pollution index > 0.7) where it needs to take measures to prevent and control as a focused object.
Synergetic evaluation of landscape conservation and development in karst gorge and cave scenic area, with a case in Jiuxiang gorge and cave scenic area, Yunnan Province, China
LI Yuhui, DING Zhiqiang, YU Xiaoya, CAI Hulin, LI Ming
2017, 36(3): 387-395. doi: 10.11932/karst20170313
Abstract:
The objective of the paper is to set up an evaluation index for coordinating natural conservation with socio-economic development through assessing landscape conservation and analyzing effect of landscape utilization on the social sustainable development for the improvement of landscape protection. With the case study area located in Jiuxiang gorge and cave scenic area of Yunnan Province, the assessing index system for the landscape naturality, functionality and locality was designed. Analytical results show that,(1) The naturality index of the Jiuxiang scenic area is 7.004 which falls in the index range of secondary landscapes; (2) Its functionality index is 7.58 representing a type of scenic landscape under development; (3) The locality index is 6.8 which indicates that the area is currently at a transformation stage with its industrial type shifting from scenic industry to services for local communities and local employment. According to the landscape patterns of the scenic area, four sub-areas for the landscape conservation were proposed in this study. They are respectively local plant corridor and cultural landscape conservation sub-area, gorge river landscape protection sub-area, gorge cave landscape protection and associated vegetation conservation sub-area, and sub-area of plant vegetation protection and rocky desertification control. It is suggested that the scenic area be preserved in a natural manner. Meanwhile, the local communities’ leading tourist service industry and local special products should be further developed for consolidating the socio-economic base of the communities and residents.
Space hierarchy of karst landscape in the Dabashan National Geological Park and influence of the neotectonic movement
FU Shun, KAN Aike, MA Deqin, XIAO Jin, HU Jin, LI Dehao, XU Manze, LIU Su, LI Wentao
2017, 36(3): 396-406. doi: 10.11932/karst20170314
Abstract:
The Dabashan National Geological Park hosts various types of karst landscapes and complete composition systems, of which the development and distribution are obviously controlled by the structure. This paper presents the features of karst landscapes of this park and studies the control of neotectonic movement on its spatial hierarchy. It is found that overall the karst space is characterized by intense tilting uplift, deep river incision, and canyons of low-medium mountains in subtropical zones. It can be divided into three elevation levels; the first is about 1 200 to 1 890 m, the second is 700 to 1 200 m, and the third 440 to 700 m. Such a spatial hierarchical structure reflects that overall the crust was in a relatively stable period when horizontal karst (caves)developed followed by fast crustal uplift with a small amount of vertical karst systems (sinkholes).The distribution of karst caves is adaptive with the corresponding base levels of erosion (modern riverbeds, terraces at all levels).It is inferred that the research area has experienced at least four large-scale intermittent rapid tectonic uplifts. The planation surfaces at all levels were affected the II and II episodes of the Himalayan Movement. Incision of abundant groundwater and surface water resulted in multilayer denudation platforms during these tectonic processes. During the relatively stable period of the neotectonic movement, there were adequate conditions of alternating cycle dissolution, leading to development of large-scale vertical and horizontal karst. 
Dynamic evaluation of ecological security and analysis of obstacle factors in karst tourist destinations:An example of Guilin City
BAO Qingqing, LIU Shengfeng
2017, 36(3): 407-414. doi: 10.11932/karst20170301
Abstract:
Based on the ecological security theory, this paper makes a dynamic evaluation of ecological and analysis of obstacle factors in karst tourist destinations. Using the PSR model, an index system for evaluation of ecological security in karst tourist destinations is established. Using the fuzzy synthesis, the real situations of ecological security of Guilin City in 2004-2013 are analyzed as an example. The results show that the Guilin's ecological security status from 2004 to 2013 exhibited a trend from decline to gradual rise and then keeping steady, and overall upward. During this period, the unsafe level in Guilin reduced, while the critical safety level increased, with fluctuations of small amplitude, which means that the obstacle factors of Guilin ecological security were gradually decreasing and its ecosystem had a major potential of development. However, the pressure on Guilin's ecosystem is increasing year by year, implying that a caution to the trend to deteriorate in the future. The main obstacle factors of the ecological security in Guilin are the growth rate of tourism, tourist economy density and level of comprehensive utilization of the land for tourism, tourism income per capita and the proportion of environmental protection in GDP. Therefore, this study suggests the following measures to maintain the ecological security of Guilin: controlling amount of tourism, enhancing use efficiency of tourism resources, and establishing a monitoring system of the tourism environment. 
Liquid-Liquid extraction inductively coupled plasma atomic emission spectrometer (ICP-AES) for determination of elemental sulfur in carbonate rock
QUAN Xiqiang, TAO Xin, DU Wenyue, QIN Suni, YU Jianguo
2017, 36(3): 415-418. doi: 10.11932/karst2017y20
Abstract:
Under condition of hypoxia, sulfate sulfur is reduced to sulfide sulfur in the process of carbonate deposition. Part of the sulfide is combined with organic to generate complicated organic sulfur while the majority of sulfide with metal ions to form sulfide precipitation. However, the sulfide precipitation is so unstable that can be converted to a stable pyrite through hydrogen sulfide, iron sulfide polysulfide and ferrous sulfide paths. Under the oxygen-rich condition, the sulfur-oxidizing bacteria will oxidate sulfide into elemental sulfur and the disproportionation of elemental sulfur will lead to the formation of various sulfurs which are stored in carbonate deposition.At present, a variety of methods are available for the measurement of elemental sulfur and its species. Unfortunately, only a few are useful at mg/L levels, which offer the possibility of applying them in different matrices. There are methods for the determination of elemental sulfur at trace levels, but they are often complicated and/or time-consuming. As a new analytical technique, inductively coupled plasma atomic emission spectrometry (ICP-AES) has many advantages such as high sensitivity, small matrix effects, wide linear range, good precision and a variety of elements can be measured simultaneously. In this paper, a method is proposed to analyze elemental sulfur in carbonate rock, which is determined with ICP-AES at the wave length of 180.7 nm and 182.0 nm, respectively. The linear correlation is 0.999 and the relative standard deviation (RSD) is lower than 5.0%.In this work, the pre-treatment method of the elemental sulfur in carbonate is established. We made efforts to reduce the impacts of extraction volume, ultrasonic time and digestion time on the recovery of elemental sulfur to obtain the optimal solution for elemental sulfur extraction. The optimal scheme is as follow, firstly, a 0.5 g carbonate standard sample was weighed in a 20 mL glass tube, followed by adding 5 mL hexane rapidly, 10 min of ultrasonic,intermittent 5 min, repeating two times and 30 min of cumulative ultrasonic, then stewing the filtrate for 10 min stratification. After centrifuging for 10 min, we got a supernatant and then transferred it to a Teflon crucible. They were repeated two times. Then hexane supernatant was collected and evaporated to dryness at a low temperature, 2 mL purity nitric acid was added to the Teflon crucible, then the lid cover was fixed to the cylinder barrel and then the solution was digested in an oven for 5 h at 150 ℃. Next we set the volume to 25 mL, shaking and measuring. We also conducted the blank experiments and standard addition method to obtain the recovery of elemental sulfur at 90%-110%.The results indicate that this method can meet the test requirements and can be used to determine elemental sulfur in carbonate rock.
A study on the test conditions and influence factors in online-phosphoric acid method for carbon isotopes of dissolved inorganic carbon compounds in water samples by Gas Bench II-IRMS
TANG Wei, WANG Hua, LAN Gaoyong, YANG Hui, WU Xia, TU Linling, YING Qihe
2017, 36(3): 419-426. doi: 10.11932/karst20170315
Abstract:
The objects of this paper is to determine the test conditions and influencing factors in online-phosphoric acid method by using Gas Bench II-IRMS for carbon isotopes of dissolved inorganic carbon compounds in water samples. The equilibrium time, chromatographic column, sample condition, sample volume and the reaction temperature were analyzed comprehensively. The conclusions were as follows, (1) The best equilibrium time of the dissolved inorganic carbon isotope in the water sample was identified. (2)There is obviously positive correlation between inorganic carbon concentration and the sample test signal intensity. (3) In the process of sample testing, the temperature of chromatographic column can not only affect the appearance time of sample peak, but also affect the peak width ,peak height and the peak area, leading to different degrees of isotope fractionation. The samples should be kept under 25 ℃ in the reaction process, meanwhile, ±1 ℃ difference in temperature between room temperature and constant temperature sample plate is required .If the temperature difference is too large, there will be water vapor in the sample vial, which will not only lead to the isotope fraction of the sample, but also affect the service life of taking gas needle even lead to serious gas needle blocking. This method can be used to analyze the δ13C values of dissolved inorganic carbon in groundwater, surface water and meteoric water.