• Included in CSCD
  • Chinese Core Journals
  • Included in WJCI Report
  • Included in Scopus, CA, DOAJ, EBSCO, JST
  • The Key Magazine of China Technology
Volume 32 Issue 2
Jun.  2013
Turn off MathJax
Article Contents
KONG Xiang sheng, QI Shi hua. The existing conditions of PAHs in multimedium in typical karst area:A case in the Leye Tiankeng Group, Guangxi[J]. CARSOLOGICA SINICA, 2013, 32(2): 182-188. doi: 10.3969/j.issn.1001-4810.2013.02.009
Citation: KONG Xiang sheng, QI Shi hua. The existing conditions of PAHs in multimedium in typical karst area:A case in the Leye Tiankeng Group, Guangxi[J]. CARSOLOGICA SINICA, 2013, 32(2): 182-188. doi: 10.3969/j.issn.1001-4810.2013.02.009

The existing conditions of PAHs in multimedium in typical karst area:A case in the Leye Tiankeng Group, Guangxi

doi: 10.3969/j.issn.1001-4810.2013.02.009
  • Received Date: 2012-12-06
  • Publish Date: 2013-06-25
  • Based on the data of dry and wet atmospheric deposition, air, soil, groundwater and sediment samples gathered during the same term from 2007 to 2008 in a typical karst area - the Dashiwei Tiankeng, contrastive analysis is done in light of the component spectrums, the distribution features and the characteristic ratio as well as their chemical and physical properties of 16 kinds of PAHs. The results show that 4 kinds of PAHs with 4~6 rings ( chrysenes, benzo[b]fluoranthene, benzo[k]fluoranthene and benzo[a]pyrene) are dominated in the annual dry and wet atmospheric deposition, soil and sediment of the underground river. And 4 kinds of PAHs with 2~3 rings ( naphthalenes, fluorene, phenanthrene and anthracene) are dominated in dry and wet atmospheric deposition in autumn and winter, air and underground river water. The existing conditions of PAHs are of better consistency but also certain differences in each medium. By means of this method it is preliminary explained the sources or input of PAHs contaminant in soil, water and underground river sediment in karst area, and proved that the dry and wet atmospheric deposition is the main pollution source in soil and the underground river in remote karst mountain area. Therefore, it is suggested that the atmospheric dry and wet deposition should be taken as a PAHs source in the investigation of pollution sources.

     

  • loading
  • [1]
    IARC (International Agency for Research on Cancer). Monographs on the Evaluation of Carcinogenic Risks to Humans[M].Lyon:1991.43-53.
    [2]
    Menzie C A, Potocki B P, Santodonato J. Exposure to carcinogenic PAHs in the environment[J].Environmental Science and Technology, 1992,26:1278-1284.
    [3]
    Hoffr M, Strachan W M J, Sweet C W, et al. Atmospheric deposition of toxic chemicals to the Great Lakes: a review of data through 1994[J].Atmospheric Environment,1996,30:3505-3527.
    [4]
    李大通.中国碳酸盐岩分布面积的测量[J].中国岩溶,1983,2(2):147-150.
    [5]
    Bidleman T F, Andi D Leone.Soil-air exchange of organochlorine pesticides in the Southern United States[J].Environmental Pollution,2004,128:49-57.
    [6]
    Daly G L, Wania F. Organic contaminants in mountains[J].Environmental Science and Technology, 2005, 39(2):385-398.
    [7]
    Jones KC, Voogt P de .Persistent organic pollutants(POPs):state of the science[J].Environmental Pollution,1999,100:209-221.
    [8]
    祁士华,张 干,刘建华,等.拉萨市城区大气和拉鲁湿地土壤中的多环芳烃[J].中国环境科学 2003,23(4):349-352.
    [9]
    Crispin J,Halsall.Investigating the occurrence of persistent organic pollutants (POPs) in the arctic:their atmospheric behaviour and interaction with the seasonal snow pack[J].Environmental Pollution,2004,128:163-175.
    [10]
    Jun Li,Hairong Cheng,Gan Zhang,et al.Polycyclic aromatic hydrocarbon (PAH) deposition to and exchange at the air-water interface of Luhu, an urban lake in Guangzhou, China[J].Environmental Pollution,2009,157:273-279.
    [11]
    Anna Palm,Ian Cousins,Orjan Gustafsson,et al.Evaluation of sequentially - coupled POP fluxes estimated from simultaneous measurements in multiple compartments of an air-water-sediment system[J].Environmental Pollution, 2004, 128:85-97.
    [12]
    孔祥胜,祁士华,黄保健,等.广西乐业大石围天坑群多环芳烃的干湿沉降[J].环境科学,2012,33(3):746-753.
    [13]
    孔祥胜,祁士华,孙骞,等. 广西大石围天坑中多环芳烃的大气传输与分异[J].环境科学,2012,33(12):72-79.
    [14]
    孔祥胜,祁士华,蒋忠诚,等.广西大石围巨型漏斗土壤中多环芳烃与环境因素[J].环境科学,2012,33(11):221-231.
    [15]
    孔祥胜,祁士华,Oramah I T,等.广西大石围天坑群地下河水中多环芳烃的污染特征[J].环境科学,2011, 32(4):1081-1087.
    [16]
    孔祥胜,祁士华,Oramah I T等.广西百朗地下河沉积物中PAHs的污染特征[J].环境科学与技术,2011,34(8):42-48.
    [17]
    朱学稳,黄保健,朱德浩,等.广西乐业大石围天坑群发现 探测 定义与研究[M].南宁:广西科学技术出版社,2003:1-17.
    [18]
    McKenzie C H Lim, Godwin A Ayoko, Lidia Morawska. Characterization of elemental and polycyclic aromatic hydrocarbon compositions of urban air in Brisbane[J].Atmospheric Environment, 2005, 39: 463- 476.
    [19]
    Doong R, Lin Y T. Characterization and distribution of polycyclic aromatic hydrocarbon contaminations in surface sediment and water from Gao-ping River,Taiwan[J]. Water Research, 2004, 38: 1733- 1744.
    [20]
    环境保护部.国家污染物环境健康风险名录——化学第一分册[M].北京:中国环境科学出版社,2009:324-330.
    [21]
    Yunker M B,Macdonald R W, Vingarzan R, et al. PAHs in the Fraser River Basin:a critical appraisal of PAH ratios as indicators of PAH source and composition[J].Organic Geochemistry,2002,33(4):489 -515.
    [22]
    Baumard P, Budzinski H, Garrigue P. Polycyclic aromatic hydrocarbons in sediments and mussels of the western Mediterranean Sea[J]. Environ. Toxicol. Chem.,1998, 17: 765-776.
    [23]
    Grimalt J O,Van Drooge B L,Ribes A,et al. Polycyclic aromatic hydrocarbon composition in soils and sediments of high altitude lakes[J]. Environmental Pollution,2004,131:13-24.
    [24]
    Hung H T P, Blancharda C J, Halsallb T F, et al. Temporal and spatial variabilities of atmospheric polychlorinated biphenyls (PCBs), organochlorine (OC) pesticides and polycyclic aromatic hydrocarbons (PAHs) in the Canadian Arctic:Results from a decade of monitoring[J]. Science of the Total Environment, 2005,342:119-144.
    [25]
    Wild S R, Jones K C.Polynuclear aromatic hydrocarbons in the United Kingdom environment: a preliminary source inventory and budget[J]. Environmental Pollution 1995, 88: 91-108.
    [26]
    Gevao B, Semple K T, Jones K C, et al. Bound pesticide residue in soils: a review[J]. Environmental Pollution, 2000,108: 3-14.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (2876) PDF downloads(1931) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return