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Volume 30 Issue 3
Sep.  2011
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ZHOU Hou-yun, TANG Jing, YUAN Dao-xian. Rare earth element contents in speleothem determined by two dissolution methods[J]. CARSOLOGICA SINICA, 2011, 30(3): 341-347. doi: 10.3969/j.issn.1001-4810.2011.03.017
Citation: ZHOU Hou-yun, TANG Jing, YUAN Dao-xian. Rare earth element contents in speleothem determined by two dissolution methods[J]. CARSOLOGICA SINICA, 2011, 30(3): 341-347. doi: 10.3969/j.issn.1001-4810.2011.03.017

Rare earth element contents in speleothem determined by two dissolution methods

doi: 10.3969/j.issn.1001-4810.2011.03.017
  • Received Date: 2011-05-03
  • Publish Date: 2011-09-25
  • Rare earth elements (REE) in stalagmite SJ3 collected from NE Sichuan in central China were determined by two dissolving methods, one by 2% HNO3 and the other by a mixture of HF and HNO3. The results indicate that although detrital materials are common in speleothems, a complete dissolution of the calcite powder from SJ3 by HF + HNO3 does not significantly enhance the REE concentrations obtained. This suggests that REEs in SJ3 are not contained in resistant silicate minerals which may not be derived from the overlying soil layer directly. The REEs in SJ3 may be released from the soil under chemical weathering, adsorbed on the surfaces of colloidal and particle materials in karst groundwater and incorporated into SJ3. The results indicated that REE in SJ3 can be released with diluted acids.

     

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  • [1]
    Wang Y J, Cheng H, Edwards R L, et al. A high-resolution absolute-dated late Pleistocene monsoon record from Hulu Cave, China[J]. Science, 2001, 294:2345-2347.
    [2]
    Yuan D X, Cheng H, Edwards R L, et al. Timing, duration, and transitions of the Last Interglacial Asian Monsoon[J]. Science, 2004, 304:575-578.
    [3]
    Zhang P Z, Cheng H, Edwards R L, et al. A test of climate, sun, and culture relationships from an1810-Year Chinese cave record[J]. Science, 2008, 322:940-942.
    [4]
    Cheng H, Edwards R L, Broecker W S, et al. Ice age terminations[J]. Science, 2009, 236:248-252.
    [5]
    Hu C Y, Huang J H, Fang N Q, et al. Adsorbed silica in stalagmite carbonate and its relationship to past rainfall[J]. Geochimica et Cosmochimica Acta, 2005, 69:2285-2292.
    [6]
    Li H C, Ku T L, You C F, et al. 87Sr/86Sr and Sr/Ca in speleothems for paleoclimate reconstruction in Central China between70 and280 kyr ago[J]. Geochimica et Cosmochimica Acta, 2005, 69:3933-3947.
    [7]
    Zhou HY, Chi B Q, Lawrence M, et al. High resolution and precisely dated record of weathering and hydrological dynamics recorded by manganese and rare earth elements in a stalagmite from central China[J]. Quaternary Research, 2008, 69:438-446.
    [8]
    Zhou H Y, Feng Y X, Zhao J X, et al. Deglacial variations of Sr and 87Sr/86Sr ratio recorded by a stalagmite from Central China and their association with past climate and environment[J]. Chemical Geology, 2009, 268:233-247.
    [9]
    Fairchild I J Pauline C T. Trace elements in speleothems as recorders of environmental change[J]. Quaternary Science Reviews, 2009, 28:449-469.
    [10]
    Clemens S C, Prell W L, Sun Y, et al. Orbital-scale timing and mechanisms driving Late Pleistocene Indo-Asian summer monsoons: Reinterpreting cave speleothemd18 O[J]. Paleoceanography, 2010, 25:PA4207, doi: 10.1029/2010PA001926.
    [11]
    Dayem K E, Molnar P, Battisti D S, et al. Lessons learned from oxygen isotopes in modern precipitation applied to interpretation of speleothem records of paleoclimate from eastern Asia[J]. Earth and Planetary Science Letters, 2010, 295:219-230.
    [12]
    Cullers R L, Basu A, Suttner L J. Geochemical signature of provenance in sandsize mineral in soil and stream near the tabacco root batholith, Montana, USA[J]. Chemical Geology, 1988, 70:335-348.
    [13]
    Murray RW, Brink M R, Brumsack H J, et al. REE in Japan Sea sediments and diagenetic behavior of Ce/Ce *: Results from O DP Log127[J]. Geochimica et Cosmochimica Acta, 1991, 55:2453-2466.
    [14]
    Richter D K, G?tte T, Niggemann S, et al. REE3+ and M n2+ activated cathodoluminescence in lateglacial and Holocene stalagmites of central Europe: evidence for climatic processes[J]. The Holocene, 2004, 14:759-767.
    [15]
    Borsato A, Frisia S, Fairchild I J, et al. Trace element distribution in annual stalagmite laminae mapped by micrometer resolution X-ray fluorescence: implications for incorporation of environmentally significant species[J]. Geochimica et Cosmochimica Acta, 2007, 71:1494-1512.
    [16]
    Zhou H Y, Wang Q, Zhao J X, et al. Rare earth elements and yttrium in a stalagmite from Central China and potential paleo climatic implications[J]. Palaeogeography, Palaeoclimatology, Palaeoecology, 2008, 270:128-138.
    [17]
    Tessier A, Campbll P G C, Bisson M. Sequential extraction procedure for speciation of particulate trace metals[J]. Analytical Chemistry, 1979, 51:844-851.
    [18]
    Elderfield H, Upstill-Goddard R, Sholkovitz E R. The rare earth elements in rivers, estuaries, and coastal seas and their significance to the composition of ocean waters[J]. Geochimica et Cosmochimica Acta, 1990, 54:971-991.
    [19]
    Sholkovitz E R. Chemical evolution of rare earth elements: fractionation between colloidal and solution phases of filtered river water[J]. Earth and Planetary Science Letters, 1992, 114:77-84.
    [20]
    Tanizaki Y, Shimokawa T, Nakamura M. Physicochemical speciation of trace elements in river waters by size fractionation[J]. Environmental Science and Technology, 1992, 26:1433-1444.
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