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Volume 29 Issue 4
Dec.  2010
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Article Contents
KONG Xiang-sheng, QI Shi-hua, Oramah I T, ZHANG Yuan, HUANG Bao-jian. Distribution of organichlorine pesticide in the water and sediment of the Bailang Subterranean Stream in Guangxi[J]. CARSOLOGICA SINICA, 2010, 29(4): 363-371. doi: 10.3969/j.issn.1001-4810.2010.04.003
Citation: KONG Xiang-sheng, QI Shi-hua, Oramah I T, ZHANG Yuan, HUANG Bao-jian. Distribution of organichlorine pesticide in the water and sediment of the Bailang Subterranean Stream in Guangxi[J]. CARSOLOGICA SINICA, 2010, 29(4): 363-371. doi: 10.3969/j.issn.1001-4810.2010.04.003

Distribution of organichlorine pesticide in the water and sediment of the Bailang Subterranean Stream in Guangxi

doi: 10.3969/j.issn.1001-4810.2010.04.003
  • Received Date: 2010-09-02
  • Publish Date: 2010-12-25
  • In order to understand distribution of organochlorine pesticide in the water and sediments of the Bailang Subterranean Stream in typical karst area in Leye, Guangxi, the water and sediment samples on different sections are collected and 19 kinds of OCPs are detected with GC-ECD. The results show that,(1)The total organochlorine pesticides concentration(∑OCPs) in the surface water of the Bailang subterranean stream ranges from 1.95 to 71.45ng/L, the concentration of HCHs ranges from undetectable to 58.40ng/L, and DDTs undetectable to 0.44ng/L respectively. (2)The concentration of∑OCPs in the sediment ranges from 0.75 to 14.85ng/L, HCHs from 0.11 to 3.52ng/L, and DDTs from 0.03 to 2.90ng/L. (3)Distributions of OCPs in water and sediment from the Bailang Subterranean Stream are related with adsorption, temperature and the soil erosion at the bottom of Tiankeng where connected with subterranean stream. Namely, OCPs of atmospheric sedimentation is easily gathered in soil at the bottom of Tiankeng for temperature difference effect (this is “cool trap effect”), and then, OCPs moves toward the water body so that concentration of ∑OCPs in sediment of the subterranean stream increases. (4)It is inferred that the OCPs in the sediment of the subterranean stream could be released to cause secondary pollution for the value of the sediment adsorption coefficient being lowest at the exit of the stream, but higher in concentration and kinds of OCPs in the stream water. (5)The ecological risk is at the low risk due to concentrations of the endrin on most sections and both DDTs and DDD on the section of the Leye County surrounding areas range between effects range to low(ERL) and effects range to median(ERM). (6)There are both newly HCHs and DDTs inputs recently on some sections. Organochlorine pesticide has accumulated for along time, which may be cause harm to the underground river ecosystem. Therefore, local government should take preventive measure.

     

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  • [1]
    Zhao ling, Ma yong jun. Analysis of organochlorine pesticides residues annlysis in agricultural environment[J]. Agriculture Environment and Development, 2001, 1(1): 37-39.
    [2]
    Moreno Fryas, Agarrido Frenich, J L Martynez Vidal, et al. Analysis of lindane, vinclozolin, aldrin, o,p'-DDT, p,p'-DDT, p,p'-DDD, p,p'-DDE, o,p'-DDT in human serum using gas chromatography with electron capture detection and tandem spectrometry[J].Journal ChromatographyB,2001,760:1-15.
    [3]
    Ratcliff D A. Changes attributable to pesticides in egg break-age frequency and eggshell thickness in some Britsh birds[J].AppliedEcology,1970,7:67-115.
    [4]
    张伟玲,张干,祁士华,等.西藏错鄂湖和羊卓雍湖水体及沉积物中有机氯农药的初步研究[J].地球化学,2003,32(4):364-367.
    [5]
    张菲娜,祁士华,苏秋克,等.福建兴化湾水体有机氯农药污染状况[J].地质科技情报,2006,25(4):77-81.
    [6]
    蒋新,许士奋,MartensD,等.长江南京段水、悬浮物及沉积物中多氯有毒有机污染物[J].中国环境科学,2000,20(3):193-197.
    [7]
    Fernandez M A, Alonso C, Gonzalez M J, et al. Occurrence of organochlorine insecticides, PCBs and PCB congeners in waters and sediments of the Ebro River(Spain)[J].Chemosphere,1999,38:33-43.
    [8]
    杨清书,麦碧娴,傅家谟,等.珠江干流河口水体有机氯农药的研究[J].中国环境科学,2005,25(Suppl.):47-51.
    [9]
    杨梅,张俊鹏,蒲俊兵,等.重庆典型岩溶区地下河水体有机氯农药初步研究[J].中国岩溶,2009,28(2):144-148.
    [10]
    袁旭音,王禹,陈骏,等.太湖沉积物中有机氯农药的残留特征及风险评估[J].环境科学,2003,24(1):122-125.
    [11]
    Zhou J L, Maskaoui K, Qiu W, et al. Polychlorinated biphenyl congeners and organochlorine insecticides in the water column and sediments of DayaBay[J]. China. Environmental Pollution,2001,113:373-384.
    [12]
    许士奋,蒋新,冯建,等.气相色谱法测定长江水体悬浮物和沉积物有机氯农药的残留量[J].环境科学学报,2000,20(4):494-498.
    [13]
    Rawn D F K, Lackhart W L, Wilkinson P. Historical contamination of Yukon lake sediments by PCBs and organochlorine pesticides: influence of local sources and watershed characteristic[J]. Sciences of the Total Environment, 2001, 280 (1-3): 17-37.
    [14]
    杨梅,蒲俊兵,张俊鹏,等.重庆典型岩溶区地下河表层沉积物OCPs初步研究[J].环境工程学报,2009,3(7):1340-1344.
    [15]
    郭红秀,陈尔,黄冠星,等.珠江三角洲地区浅层地下水中有机氯农药的污染特征[J].环境化学,2006,25(6):798-799.
    [16]
    袁道先,蔡桂鸿.岩溶环境学[M].重庆:重庆出版社,1988.40-44,71-88.
    [17]
    朱学稳,黄保健,朱德浩,等.广西乐业大石围天坑群发现探测定义与研究[M].南宁:广西科学技术出版社,2003:1-17.
    [18]
    林峥,麦碧娴,张干,等.沉积物中多环芳烃和有机氯农药定量分析的质量保证和质量控制[J].环境化学,1999,18(2):115-121.
    [19]
    Middeldrop P J M, Jaspers M, Zehnder A J B, et al. Biotrans formation of α-,β-,g-,d- Hexachloro cyclohexane under methanogenic conditions[J]. Environmental Science and Technology, 1996, 30:2345-2349.
    [20]
    Waller K, Vallero D A, Lewis R G. Factor influencing the distribution of lindane and other hexachloro cyclohexane in the environment[J]. Environmental Science and Technology, 1999,33(24):4373-4378.
    [21]
    Wilfre d E, Perreira D, et al. Occurrence and accumulation of pesticides and organic contaminants in river, sediment, water and clam issue from the SanJoaquin river and tributaries, California[J]. Environmental Toxicology and Chemistry, 1996, 15(2):172-180.
    [22]
    余刚,牛军峰,黄俊.持久性有机污染物———新的全球性环境问题[M].北京:科学出版社2005:107-125.
    [23]
    K C Jones, PdeVoogt. Persistent organic pollutants (POPs): state of the science [J]. Environmental Pollution, 1999, 100:209-221.
    [24]
    何才华,王宗艳.洞穴环境与洞穴旅游[C]//陈伟海,朱德浩,朱学稳.洞穴探险、研究、开发与保护———全国洞穴学术会议论文选集.北京:地质出版社,2008.320-322.
    [25]
    Long E R, Macdonald D D, Smith S L, et al. Incidence of adverse biological effects with ranges of chemical concentrations in marine and estuarine sediments [J]. Environmental Management, 1995, 19(1):81-97.
    [26]
    Long E D, Field L J, MacDonald D D. Predicting toxicity marine sediments with numerical sediment quality guide lines [J]. Environmental Toxicological Chemistry, 1998,17(4):714-727.
    [27]
    Ingersoll C G. Calculation and evaluation of sediment effect concentrations for the amphipod Hyalella azteca and the midge Chironomus riparius[J]. Great Lakes Research, 1996, 22:602-623.
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