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Volume 37 Issue 6
Dec.  2018
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Article Navigation >  CARSOLOGICA SINICA  > 2018  >  37(6): 875-882
ZHONG Cong, WANG Cheng, LI Jie, HUANG Jinlan, CHEN Meijun, HE Ping, ZHANG Xinying, HU Baoqing. Arsenic vertical distribution and its controlling factors in paddy soil profiles in a typical karst area, northwest of Guangxi, China[J]. CARSOLOGICA SINICA, 2018, 37(6): 875-882.
Citation: ZHONG Cong, WANG Cheng, LI Jie, HUANG Jinlan, CHEN Meijun, HE Ping, ZHANG Xinying, HU Baoqing. Arsenic vertical distribution and its controlling factors in paddy soil profiles in a typical karst area, northwest of Guangxi, China[J]. CARSOLOGICA SINICA, 2018, 37(6): 875-882.
shu

Arsenic vertical distribution and its controlling factors in paddy soil profiles in a typical karst area, northwest of Guangxi, China

  • 1.

    Key Laboratory of Beibu Gulf Environment Change and Resources Use(MOE)/ Key Laboratory of Earth Surface Processes and Intelligent Simulation, Guangxi Teachers Education University, Nanning, Guangxi 530001, China

  • 2.

    School of Environmental Sciences and Engineering, Nanjing University of Information Science and Technology, Nanjing,Jiangsu 210044, China

  • 3.

    Guangxi Institute of Geological Survey, Nanning, Guangxi 530023, China

  • 4.

    School of Geography and Planning, Guangxi Teachers Education University, Nanning,Guangxi 530001, China

  • Publish Date: 2018-12-25
    Abstract
  • The characteristics of topsoil soil arsenic (As) accumulation and vertical migration in karst areas is of great significance to understand the migration and transformation of soil As and its geochemical behavior in soil environment. To explore the concentrations and migration characters of As in karst region, three paddy soil profiles in a typical karst mining area, northwest of Guangxi, were investigated and analyzed. This study area is located in the Dachang mining area in the southwestern part of Nandan district, characterized by the south-middle subtropical monsoon climate. The contents of the soil samples collected from the soil profiles were analyzed in a geochemistry laboratory,where the soil As concentrations were analyzed using the atomic fluorescence spectrometric method; the concentrations of MgO, K2O, CaO and Na2O were analyzed using ICP spectrometric method; the soil organic carbon concentrations were analyzed using redox volumetric method; and the soil pH was analyzed using ion selective electrode method. Afterward, the statistical software SPSS was applied to perform the data analyses, combined with the background of study area. Results show that the soil profiles consists of limestone soils with high degree of chemical weathering originated from soil parent materials. The soil As concentration in all the profiles studied has similar character, with relatively high As levels near the surface which becomes stable at the deeper portions of the soil. The dominant controlling factor of As migration and transformation was considered to be the soil organic carbon. In the periphery of the mine, the analytical result of two soil samples shows that the soil As mainly concentrated at the depth of 10-20 cm, rather than 0-10 cm . The mean concentrations of soil As in these soil profiles are 5.5 mg·kg-1 and 5.0 mg·kg-1 , respectively, with the ranges of 2.7 mg·kg-1 -9.9 mg·kg-1 and 2.5 mg·kg-1 -8.5 mg·kg-1 . The soil As concentrations of the profile closer to the mining area are characterized by high As background value, and the mean concentration of soil As is 46.2 mg·kg-1 ranging from 34.2 mg·kg-1 to 84.5 mg·kg-1 . The higher soil As concentrations in this soil profile gathers at the depth of 20-40 cm，while it is relatively lower in 10-20 cm deep. Notably, the soil As concentrations in this soil profile at 0-10 cm is also significantly higher than that of 10-20 cm deep, indicating that exogenous sources had significant effects on the surface soil of this profile. The ecological environment of karst mining area is extremely vulnerable, and the issue of agricultural soil As pollution in the surrounding areas should be paid sufficient attentions.

     

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    • References(36)
  • [1]
    肖细元，陈同斌，廖晓勇，等. 中国主要含砷矿产资源的区域分布与砷污染问题［J］. 地理研究, 2008，27(1): 201-212.
    [2]
    黎勇, 钟格梅, 黄江平, 等. 2011-2013年广西农田土壤砷调查［J］. 环境与健康杂志, 2015, 32(2):129-131.
    [3]
    Shi Y, Chen WQ, Wu S,et al. Anthropogenic cycles of arsenic in mainland China: 19902010［J］. Environmental Science & Technology, 2017, 51(3): 1670-1678.
    [4]
    宋贤威, 高扬, 温学发,等. 中国喀斯特关键带岩石风化碳汇评估及其生态服务功能［J］. 地理学报, 2016, 71(11):1926-1938.
    [5]
    阮玉龙, 李向东, 黎廷宇,等. 喀斯特地区农田土壤重金属污染及其对人体健康的危害［J］. 地球与环境, 2015, 43(1):92-97.
    [6]
    Matschullat J. Arsenic in the geosphere-a review.［J］. Science of the Total Environment, 2000, 249(1-3):297.
    [7]
    Mandal B K, Suzuki K T. Arsenic round the world: a review.［J］. Talanta, 2002, 58(1):201-235.
    [8]
    钟雪梅, 于洋, 陆素芬,等. 金属矿业密集区广西南丹土壤重金属含量特征研究［J］. 农业环境科学学报, 2016, 35(9):1694-1702.
    [9]
    余元元, 黄宇妃, 宋波,等. 南丹县矿区周边土壤与农产品重金属含量调查及健康风险评价［J］. 环境化学, 2015, 34(11):2133-2135.
    [10]
    宋波, 刘畅, 陈同斌. 广西土壤和沉积物砷含量及污染分布特征［J］. 自然资源学报, 2017, 32(4):654-668.
    [11]
    邓琴, 吴迪, 秦樊鑫,等. 岩溶铅锌矿区土壤重金属污染特征［J］. 中国岩溶, 2017, 36(2):248-254.
    [12]
    蔡刚刚, 张学洪, 梁美娜,等. 南丹大厂矿区周边农田土壤重金属健康风险评价［J］. 桂林理工大学学报, 2014, 34(3):554-559.
    [13]
    Zhang X Y, Tang L S, Zhang G, et al. Heavy metal contamination in a typical mining town of a minority and mountain area, South China.［J］. Bulletin of Environmental Contamination & Toxicology, 2009, 82(1):31-38.
    [14]
    Zhang X Y, Lin Q, Jin M, et al. Heavy metal contamination and spatial distribution of agricultural soil and vegetables in a village of a mining area in Guangxi, China［J］. BioTechnology, 2014, 10(7):1804-1811.
    [15]
    宋书巧, 梁利芳, 周永章,等. 广西刁江沿岸农田受矿山重金属污染现状与治理对策［J］. 矿物岩石地球化学通报, 2003, 22(2):152-155.
    [16]
    刘永轩, 黄泽春, 蹇丽,等. 广西刁江沿岸土壤As, Pb和Zn污染的分布规律差异［J］. 环境科学研究, 2010, 23(4):485-490.
    [17]
    刘畅, 宋波, 张云霞,等.西江流域土壤砷含量空间变异与污染评价［J］. 环境科学, 2018, 39(2): 899-908.
    [18]
    洪涛, 谢运球, 赵一,等. 硫铁矿冶炼区不同土地利用方式及土壤类型对重金属迁移的影响［J］. 中国岩溶, 2016, 35(4):439-445.
    [19]
    Lin C, Wang J, Cheng H, et al. Arsenic profile distribution of the wetland argialbolls in the Sanjiang Plain of northeastern China［J］. Scientific Reports, 2015, 5:10766.
    [20]
    张国祥, 杨居荣, 华珞. 土壤环境中的砷及其生态效应［J］. 土壤, 1996(2):64-68.
    [21]
    魏复盛, 陈静生, 吴燕玉,等. 中国土壤环境背景值研究［J］. 环境科学, 1991,12(4):12-19.
    [22]
    雷亚超, 张学洪, 叶丽丽,等. 广西典型高砷背景地区石漠化土壤中砷形态及相关因子研究［J］. 生态环境学报, 2017, 26(2):335-341.
    [23]
    Zhang H H, Yuan H X, Hu Y G, et al. Spatial distribution and vertical variation of arsenic in Guangdong soil profiles, China.［J］. Environmental Pollution, 2006, 144(2):492-499.
    [24]
    邹强. 重庆紫色土中砷含量分布及主要行为特征研究［D］. 重庆：西南大学, 2009.
    [25]
    张春荣, 庞绪贵, 高宗军,等. 鱼台区域土壤中砷的分布特征及其成因分析［J］. 安徽农业科学, 2010, 38(11):5755-5757,5820.
    [26]
    Jiang W, Hou Q, Yang Z, et al. Evaluation of potential effects of soil available phosphorus on soil arsenic availability and paddy rice inorganic arsenic content.［J］. Environmental Pollution, 2014, 188(5):159-165.
    [27]
    Fu Y, Chen M, Bi X, et al. Occurrence of arsenic in brown rice and its relationship to soil properties from Hainan Island, China［J］. Environmental Pollution, 2011, 159(7):1757-1762.
    [28]
    陈骏, 季峻峰, 仇纲,等. 陕西洛川黄土化学风化程度的地球化学研究［J］. 中国科学(D辑：地球科学）, 1997, 27(6):531-536.
    [29]
    冯连君, 储雪蕾, 张启锐,等. 化学蚀变指数(CIA)及其在新元古代碎屑岩中的应用［J］. 地学前缘, 2003, 10(4):539544.
    [30]
    廖晓勇, 陈同斌, 肖细元,等. 污染水稻田中土壤含砷量的空间变异特征［J］. 地理研究, 2003, 22(5):635-643.
    [31]
    张新英, 赵才流, 吴浩东,等. 广西一个典型矿业镇环境中重金属污染分析［J］. 中国环境监测, 2008, 24(4):79-83.
    [32]
    Jiang W, Hou Q, Yang Z, et al. Annual input fluxes of heavy metals in agricultural soil of Hainan Island, China［J］. Environmental Science and Pollution Research, 2014, 21(13):7876-7885.
    [33]
    Hou Q, Yang Z, Ji J, et al. Annual net input fluxes of heavy metals of the agro-ecosystem in the Yangtze River delta, China［J］. Journal of Geochemical Exploration, 2014, 139(1):68-84.
    [34]
    Lei L, Ma Y B, Zhang S Z, et al. An inventory of trace element inputs to agricultural soils in China.［J］. Journal of Environmental Management, 2009, 90(8):2524-2530.
    [35]
    李秋言, 赵秀兰. 紫色水稻土颗粒有机质对重金属的富集特征［J］. 环境科学,2017,38(5):2146-2153.
    [36]
    杨四坤, 祖艳群, 李元,等. 云南辣椒种植区土壤中总砷的水平分布特征及其影响因素分析［J］. 云南农业大学学报(自然科学), 2014, 29(3):380-385.
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