Isotope analysis on the source of nitrate contamination to groundwater in the Dong’e hydrogeologic unit
-
摘要: 针对近年来地下水硝酸盐污染日益严重的现象,本文运用氮同位素技术对位于典型农业区的东阿水文地质单元地下水氮污染来源进行了研究,结果表明:浅层地下水监测点的NO3-含量较高,平均含量为27.77 mg·L-1 ,δ15N 为7.8‰~12‰,反映了浅层地下水主要受到生活污水或粪便的污染;深层地下水(岩溶水)中NO3- 含量相对较低,平均含量为12.81 mg·L-1,δ15N为7.2‰~14.3‰,同样指示为生活污水或粪便污染,与补给区人为干扰密切相关。部分监测点地下水质量较差,建议研究区内使用高效的灌溉技术及科学的施肥方式,补给区附近的家禽养殖场可通过修建发酵池和改善饲料配方等方式,从源头上降低地下水硝酸盐的输入量。Abstract: In recent years, nitrate pollution to groundwater has been increasingly serious, In this work, nitrogen isotope technique was used to study such pollution in a typical agricultural area of the Dong’e hydrogeological unit. The results show that the content of NO3- at monitoring sites of shallow groundwater is high with average content of 27.77 mg·L-1; and the content of δ15N is between 7.8‰ to 12‰, indicating the shallow groundwater is contaminated by sewage or feces. NO3- content of deep groundwater (karst water) is relatively low with an average value 12.81 mg·L-1, and the content of δ15N is in 7.2‰-14.3‰ also indicating sewage or fecal contamination, closely related to human disturbance. The groundwater quality of some monitoring sites is poor. It is suggested that efficient irrigation technology and scientific fertilization should be used in the study area, poultry farms can be built through fermentation tanks and improved feed formulations, thus to reduce the exogenous input of groundwater nitrate from the source.
-
Key words:
- nitrogen isotope /
- groundwater /
- nitrogen pollution source /
- agricultural area
-
[1] Wang J L, Yang Y S. An approach to catchment-scale groundwater nitrate risk assessment from diffuse agricultural sources: A case study in the Upper Bann, Northern Ireland[J]. Hydrological Processes, 2008, 22(21):4274-4286. [2] Nixdorf E, Sun Y Y, Lin M, et al. Development and application of a novel method for regional assessment of groundwater contamination risk in the Songhua River Basin[J]. Science of The Total Environment, 2017, 605:598-609. [3] Jones R R , Weyer P J , Dellavalle C T , et al. Nitrate from Drinking Water and Diet and Bladder Cancer Among Postmenopausal Women in Iowa[J]. Environmental Health Perspectives, 2016, 124(11):1751-1758. [4] Li P Y, Li X Y, Meng X Y, et al. Appraising Groundwater Quality and Health Risks from Contamination in a Semiarid Region of Northwest China[J]. Exposure & Health, 2016, 8(3):361-379. [5] 杨淡,蔡鹤生,刘存富,等. NO3中15N和18O同位素新技术在岩溶地区地下水氮污染研究中的应用—以河南林州食管癌高发区研究为例[J].中国岩溶,2004,23(3):206- 212. [6] Colin M W.US report raises fears over nitrate levels in water[J].Nature,1995,377:4. [7] 张翠云, 王昭, 程旭学. 张掖市地下水硝酸盐污染源的氮同位素研究[J].干旱区资源与环境,2004,18(1):79-85. [8] 刘宏斌, 张云贵, 李志宏, 等. 北京市平原农区深层地下水硝态氮污染状况研究[J].土壤学报,2005,42(3):411-418. [9] 乔光建, 张均玲, 唐俊智.地下水氮污染机理分析及治理措施[J].水资源保护,2004,20(3):9-12. [10] Kendall C, McDonnell JJ. Isotope tracers in catchment hydrology[J]. Elsevier Science,1998, 519-569. [11] Spalding R F, Z. K U, Hyun S W, et al. Source identification of nitrate on Cheju Island, South Korea[J]. Nutrient Cycling in Agroecosystems, 2001, 61(3):237-246. [12] Choi W J, Yoon K S, Ro H M, et al. Impact of landuse types on nitrate concentration and δ15N in unconfined groundwater in rural areas of Korea[J]. Agriculture Ecosystems & Environment, 2007, 120(2):259-268. [13] Fryar A E, Macko S A, Iii W F M, et al. Nitrate reduction during ground-water recharge, Southern High Plains, Texas[J]. Journal of Contaminant Hydrology, 2000, 40(4):335-363. [14] Krotkiewski H, Duk M, Syper D, et al. Intermittent denitrification: The application of a 15N natural abundance method to a forested ecosystem[J]. Geochimica et Cosmochimica Acta, 1997, 61(23):5043-5050. [15] 李思亮,刘丛强,肖化云,等.δ15N在贵阳地下水氮污染来源和转化过程中的辨识应用[J].地球化学,2005,34(3):257-262. [16] 庞会从,刘福亮,付海燕,等. 2009-2014 年河北平原浅层地下水硝态氮特征及其来源[J].环境工程学报,2015,9(10):4766-4772. [17] 张翠云,张胜,李政红,等. 利用氮同位素技术识别石家庄市地下水硝酸盐污染源[J].地球科学进展,2004,19(2):183-190. [18] 吴登定,姜月华,贾军远,等.运用氮、氧同位素技术判别常州地区地下水氮污染源[J]. 水文地质工程地质,2007,3:15-15. [19] 黄强盛,李清光,卢玮琦,等.滇池流域地下水、河水硝酸盐污染及来源[J]. 地球与环境,2014,42(5):589-596 [20] Singleton M J, Woods K N, Conrad M E, et al. Tracking Sources of Unsaturated Zone and Groundwater Nitrate Contamination Using Nitrogen and Oxygen Stable Isotopes at the Hanford Site, Washington[J]. Environmental Science & Technology, 2005, 39(10):3563-3570. [21] Sacchi E, Acutis M, Bartoli M, et al. Origin and fate of nitrates in groundwater from the central Po plain: Insights from isotopic investigations[J]. Applied Geochemistry, 2013, 34:164-180. [22] Heaton THE. Isotopic studies of nitrogen pollution in the hydrosphere and atmosphere: A review [J]. Chemical Geology, 1986, 59: 87-1021.Heaton T H E . Isotopic studies of nitrogen pollution in the hydrosphere and atmosphere: A review[J]. Chemical Geology, 1986, 59(2):87-102. [23] Wassenaar L. Evaluation of the origin and fate of nitrate in the Abbotsford aquifer using the isotopes of 15N and 18O in NO3[J]. Applied Geochemistry, 1995, 10: 391-405. [24] Korotkevich A Y , Kuznetsova N A , Tiunov A V . Changes in carbon and nitrogen isotope ratios (13C/12C and 15N/14N) in springtails during long-term storage of soil samples[J]. Russian Journal of Ecology, 2016, 47(6):572-574. [25] 丁京涛, 席北斗, 许其功, 等. 稳定同位素技术在地表水硝酸盐污染研究中的应用[J]. 湖泊科学, 2013,25(5):617-627. [26] Xue D M, Botte J, Baets B D, et al. Present limitations and future prospects of stable isotope methods for nitrate source identification in surface-and groundwater[J]. Water Research, 2009, 43(5):1159-1170. [27] 宋晓焱, 尹国勋, 谭利敏, 等. 污水灌溉对地下水污染的机理研究[J].安全与环境学报,2006,6(1):136-138. [28] 王玉强. 上海市域地下水环境氯离子含量的时空演化特征研究[J].山东农业大学学报(自然科学版),2015,46(6):892-897.
点击查看大图
计量
- 文章访问数: 1990
- HTML浏览量: 633
- PDF下载量: 590
- 被引次数: 0