基于主成分分析的岩溶水水化学组成及影响因素研究——以贵州水城盆地为例

叶慧君; 张瑞雪; 吴 攀; 李学先; 覃应机; 査学芳; 韩志伟

doi:10.11932/karst20170209

基于主成分分析的岩溶水水化学组成及影响因素研究——以贵州水城盆地为例

doi: 10.11932/karst20170209

1.
贵州大学资源与环境工程学院
2.
贵州大学资源与环境工程学院/国土资源部喀斯特环境与地质灾害重点实验室
3.
国土资源部喀斯特环境与地质灾害重点实验室

基金项目: 贵州省地勘基金项目（[2014]23）；国家自然科学基金委员会-贵州省人民政府喀斯特科学研究中心项目（U1612442）；黔科合LH字[2016]7456；黔教合KY字[2015]330

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出版历程
- 发布日期: 2017-04-25

Hydrogeochemical characterization of groundwater and surface water and their influencing factors based on principal component analysis: An example in the Shuicheng basin of Guizhou

1.
College of Resource and Environmental Engineering, Guizhou University
2.
College of Resource and Environmental Engineering, Guizhou University/Key Laboratory of Karst Environment and Geohazard， Ministry of Land and Resources
3.
Key Laboratory of Karst Environment and Geohazard， Ministry of Land and Resources

摘要

摘要: 2015年9月对贵州水城盆地进行采样，共采集地下水样品12个，地表水样品10个，综合运用相关性分析、主成分分析等方法，并结合PHREEQC软件对矿物饱和度指数的计算结果，探讨了地下水、地表水水化学特征现状及其影响因素。研究结果表明：水城盆地岩溶水的水化学类型主要为HCO3-Ca型，部分为SO4-Ca型，地下水和地表水水化学组成主要受Ca2+、K++Na+、HCO3-、SO42-和Cl-影响。研究区地下水和地表水中Ca2+和HCO3-主要来源于碳酸盐岩地区的水-岩反应，水体中Cl-、NO3-和Na+主要来源于城镇生活污水、屠宰废水排放。地下水水质受水-岩反应影响，部分区域受到人类活动干扰明显；地表水水质在钟山区方向主要受沿途生活污水和农业面源污水汇入影响显著，而在水城县方向受煤矿企业排放废水影响较大。
- 水化学特征 /
- 主成分分析 /
- 影响因素 /
- 水城盆地 /
- 贵州
Abstract: As the major water resources for most of the settlements in karst regions, karst water could be more easily polluted in a shorter time by human activity than water in non-karst aquifers. Assessing current hydrochemical status and understanding the mineralization process in karst water are of significance to analyze the influence factors from natural evolution and human activities. The Shuicheng basin, a tectonic basin with well-developed karst topography, is located at the center of the Yunnan-Guizhou Plateau, southwestern China. The NW-SE oriented basin is an area of approximately 22.5 km long, 5.5 km to 9 km wide and 208 km2 in size, with the elevation ranging from 1,700 m to 1,800 m above mean sea level. Climatically, it falls in the north subtropical monsoon zone with plentiful precipitation which is a major source recharging the karst water. Average annual precipitation in this area is 1,200 mm/year to 1,500 mm/year. Geologically, the basin predominantly consists of the Permian and Carboniferous carbonate rocks, accounting for nearly 90% of the total rock exposure.This work investigated the hydrogeochemical characteristics and influence factors of groundwater and surface water in different regions of the Shuicheng basin, with the intension of providing references for helping to significantly improve the quality of the aquifer. Sampling campaigns were carried out in September 2015. Variable parameters of the sampled water were measured using a portable instrument and HCO3- was titrated with 0.01 mol/L HCl in the field. All water samples were filtered through 0.45 μm cellulose acetate membrane filters and then collected into 50 mL high-density polyethylene bottles. The samples for cation analysis were immediately acidified with pure HNO3 to a pH lower than 2. The cations and anions of the samples were analyzed by the methods of atomic absorption spectrometry and ion chromatography, respectively, with the test accuracy of less than 5%.The interpretation of hydrochemical data was performed by using various methods, i.e. Piper diagram, correlation analysis, multivariate principal component analysis, and saturation mapping. The results show two hydrochemical types (HCO3-Ca and SO4-Ca) that characterize the groundwater and surface water. Natural dissolution of carbonate rock (water-rock interaction) is the primary source of Ca2+and HCO3- in groundwater and surface water. Domestic sewage and the wastewater from livestock and poultry industry may be the main contribution of Cl-,NO3-and Na+ to surface water. The main factor affecting on the quality of groundwater is the water-rock reaction. The urban sewage water from Zhongshan district and coal industrial wastewater from Shuicheng County and discharge from the groundwater are the main sources affecting the surface water quality of the basin. In conclusion, the evolution of water quality is determined by the lithology of the aquifer (dissolution and base exchanges) and by anthropogenic processes (urbanization, coal mining activities and agriculture).
- hydrochemical characteristics /
- principal component analysis (PCA) /
- influence factors /
- Shuicheng basin /
- Guizhou

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参考文献(32)

[1]	Lu Y. Karst water resources and geo-ecology in typical regions of China［J］.Environmental Geology,2006,51(5):695-699.
[2]	王顺祥，王济良.贵州省六盘水市地质灾害研究［M］.贵阳：贵州民族出版社，1998：1-2.
[3]	Wu P, Tang C, Zhu L, et al. Hydrogeochemical characteristics of surface water and groundwater in the karst basin, southwest China［J］.Hydrological Processes, 2009,23(14):2012-2022.
[4]	Romanov D, Gabrovsek F, Dreybrodt W. The impact of hydrochemical boundary conditions on the evolution of limestone karst aquifers［J］.Journal of Hydrology,2003,276(1):240-253.
[5]	Kumar M, Herbert R, Ramanathan A L, et al. Hydrogeochemical zonation for groundwater management in the area with diversified geological and land-use setup［J］.Chemie der ErdeGeochemistry, 2013,73(3): 267-274.
[6]	张红波,何师意,于奭,等. 桂江流域河流水化学特征及影响因素［J］.中国岩溶,2012,31(4):395-401.
[7]	Goldscheider N. Karst groundwater vulnerability mapping: application of a new method in the Swabian Alb, Germany［J］.Hydrogeology Journal,2003,13(4):555-564.
[8]	于奭,孙平安,杜文越,等.人类活动影响下水化学特征的影响:以西江中上游流域为例［J］.环境科学,2015,36(1):72-79.
[9]	Arunprakash M, Giridharan L, Krishnamurthy R R, et al. Impact of urbanization in groundwater of south Chennai City, Tamil Nadu, India［J］.Environmental Earth Sciences,2013,71(2):947-957.
[10]	卢海平,孔祥胜,邹胜章,等. 广西南宁朝阳溪对浅层地下水污染特征研究［J］.中国岩溶,2015,34(4):395-401.
[11]	杨泊,刘康祥.水城岩溶盆地成因及其演化［J］.贵州科学,1990,8(2):36-42.
[12]	Kau F. Review of groundwater pollution and protection in karst areas［J］.Water, Air, and Soil Pollution,1999,113(1/4):337-356.
[13]	黄奇波,覃小群,刘朋雨,等. 乌江中上游段河水主要离子化学特征及控制因素［J］.环境科学,2016,37(5):1779-1787.
[14]	黄婕,于奭,梁权.多元统计法在河水主要离子含量变化特征及来源分析中的运用：以梧州水文站控制断面为例［J］.中国岩溶,2014,33(4):412-418.
[15]	Yang P, Yuan D, Yuan W, et al. Formations of groundwater hydrogeochemistry in a karst system during storm events as revealed by PCA［J］.Chinese Science Bulletin,2010,55(14):1412-1422.
[16]	Jiang Y, Wu Y, Groves C, et al. Natural and anthropogenic factors affecting the groundwater quality in the Nandong karst underground river system in Yunnan, China［J］.Journal of contaminant hydrology,2009,109(1/4):49-61.
[17]	Han Z, Tang C, Wu P, et al. Hydrogeochemical characteristics and associated mechanism based on groundwater dating in a karstic basin, Guizhou Province, China［J］.Environmental Earth Sciences,2014,73(1):67-76.
[18]	郎赟超,刘丛强,赵志琦,等. 贵阳市地表水地下水化学组成:喀斯特水文系统水-岩反应及污染特征［J］.水科学进展,2005,16(6):826-832.
[19]	邓自民,杨明德.水城盆地岩溶水资源研究［M］ .贵阳:贵州人民出版社, 1989.
[20]	张艳梅,陈海涛,黄太林,等.近50 年六盘水市雨季降水特征分析［J］.安徽农业科学,2011,39(15):9072，9114.
[21]	韩至钧,金占省. 贵州省水文地质志［M］.北京:地震出版社,1996: 176-223.
[22]	王瑞江,姚长宏,蒋忠诚,等.贵州六盘水石漠化的特点、成因与防治［J］.中国岩溶,2001,20(3):211-216.
[23]	Touhari F, Meddi M, Mehaiguene M, et al. Hydrogeochemical assessment of the Upper Cheliff groundwater (North West Algeria)［J］.Environmental Earth Sciences,2014,73(7):3043-3061.
[24]	Carroll S, Goonetilleke A. Assessment of high density of onsite wastewater treatment systems on a shallow groundwater coastal aquifer using PCA［J］.Environmetrics,2005,16(3):257-274.
[25]	庞西磊,尹辉.阿拉善高原盐湖水化学特征的主成分分析研究［J］.地质学报,2009,29(2):199-203.
[26]	余琴,杨平恒,于正良,等.不同时间段青木关岩溶地下河水化学变化主导因素分析［J］.中国岩溶,2016,35(2):134-143.
[27]	Parkhurst D L, Appelo C A J. User’s guide to PHREEQC (Version 2): A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations［M］. Denver, Colorado: U.S. GEOLOGICAL SURVEY, 1999:196-202.
[28]	Appelo C A J , Postma D. Geochemistry, groundwater and pollution［M］. 2ed. Florida, USA: CRC Press, 2005:599-616.
[29]	Yidana S M, Ophori D, Banoeng Yakubo B. Hydrochemical evaluation of the Voltaian system—the Afram Plains area, Ghana［J］. Journal of Environmental Management,2008,88(4):697-707.
[30]	Zhai Y, Lei Y, Zhou J, et al. The spatial and seasonal variability of the groundwater chemistry and quality in the exploited aquifer in the Daxing District, Beijing, China［J］. Environmental monitoring and assessment,2015,187(43):1-15.
[31]	孙静,吴攀,韩志伟,等.高砷煤矿废水对表层岩溶水水质的影响［J］.环境科学研究,2009,22(12):1440-1444.
[32]	Li X D, Liu C Q, Harue M, et al. The use of environmental isotopic (C, Sr, S) and hydrochemical tracers to characterize anthropogenic effects on karst groundwater quality: A case study of the Shuicheng Basin, SW China［J］.Applied Geochemistry,2010,25(12):1924-1936.